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Optically active rhodium and iridium C₆₀ complexes containing the enantiomeric ligand (+)DIOP: (η²-C₆₀)MH(CO)[(+)DIOP] (M=Rh, Ir)

Marina Vladimirovna Tsikalova ¹

Marina Vladimirovna Tsikalova

Sergei Vladimirovich Zheludkov ¹

Sergei Vladimirovich Zheludkov

Eugenii Victorovich Vorontsov ¹

Eugenii Victorovich Vorontsov

Vasily Vasilevich Bashilov ¹

Vasily Vasilevich Bashilov

Kyrill Konstantinovich Babievskii ¹

Kyrill Konstantinovich Babievskii

Vyacheslav Ivanovich Sokolov ¹

Vyacheslav Ivanovich Sokolov

Yurii Nikolaevich Novikov ¹

Yurii Nikolaevich Novikov

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2011.09.008

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Published 2011-09-14

Communication , Volume 21, Issue 5, 256-258

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Tsikalova M. V. et al. Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir) // Mendeleev Communications. 2011. Vol. 21. No. 5. pp. 256-258.

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Tsikalova M. V., Zheludkov S. V., Vorontsov E. V., Bashilov V. V., Babievskii K. K., Sokolov V. I., Novikov Y. N. Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir) // Mendeleev Communications. 2011. Vol. 21. No. 5. pp. 256-258.

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TY - JOUR

DO - 10.1016/j.mencom.2011.09.008

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.09.008

TI - Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir)

T2 - Mendeleev Communications

AU - Tsikalova, Marina Vladimirovna

AU - Zheludkov, Sergei Vladimirovich

AU - Vorontsov, Eugenii Victorovich

AU - Bashilov, Vasily Vasilevich

AU - Babievskii, Kyrill Konstantinovich

AU - Sokolov, Vyacheslav Ivanovich

AU - Novikov, Yurii Nikolaevich

PY - 2011

DA - 2011/09/14

PB - Mendeleev Communications

SP - 256-258

IS - 5

VL - 21

ER -

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@article{2011_Tsikalova,

author = {Marina Vladimirovna Tsikalova and Sergei Vladimirovich Zheludkov and Eugenii Victorovich Vorontsov and Vasily Vasilevich Bashilov and Kyrill Konstantinovich Babievskii and Vyacheslav Ivanovich Sokolov and Yurii Nikolaevich Novikov},

title = {Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir)},

journal = {Mendeleev Communications},

year = {2011},

volume = {21},

publisher = {Mendeleev Communications},

month = {Sep},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.09.008},

number = {5},

pages = {256--258},

doi = {10.1016/j.mencom.2011.09.008}

}

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Tsikalova, Marina Vladimirovna, et al. “Optically active rhodium and iridium C60 complexes containing the enantiomeric ligand (+)DIOP: (η2-C60)MH(CO)[(+)DIOP] (M=Rh, Ir).” Mendeleev Communications, vol. 21, no. 5, Sep. 2011, pp. 256-258. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.09.008.

Abstract

The fullerene–metal complexes (η²-C₆₀)MH(CO)[(+)DIOP] (M=Ir, Rh) have been prepared by the exchange reaction of PPh₃ in corresponding (η²-C₆₀)MH(CO)(PPh₃)₂ for the chelate optically active ligand (+)DIOP [(+)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino)ethane] and their structures assigned.

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