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Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates

Issa Yavari 1
Issa Yavari
, 
Tayebeh Sanaeishoar 1
Tayebeh Sanaeishoar
, 
Leila Azad 1
Leila Azad
1 Department of Chemistry, Science and Research Branch, Islamic Azad Univeristy, Ponak, Tehran, Iran
10.1016/j.mencom.2011.07.020
Published 2011-07-01
Communication , Volume 21, Issue 4, 229-230
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Yavari I., Sanaeishoar T., Azad L. Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates // Mendeleev Communications. 2011. Vol. 21. No. 4. pp. 229-230.
GOST all authors (up to 50) Copy
Yavari I., Sanaeishoar T., Azad L. Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates // Mendeleev Communications. 2011. Vol. 21. No. 4. pp. 229-230.
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TY - JOUR
DO - 10.1016/j.mencom.2011.07.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.020
TI - Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates
T2 - Mendeleev Communications
AU - Yavari, Issa
AU - Sanaeishoar, Tayebeh
AU - Azad, Leila
PY - 2011
DA - 2011/07/01
PB - Mendeleev Communications
SP - 229-230
IS - 4
VL - 21
ER -
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@article{2011_Yavari,
author = {Issa Yavari and Tayebeh Sanaeishoar and Leila Azad},
title = {Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.020},
number = {4},
pages = {229--230},
doi = {10.1016/j.mencom.2011.07.020}
}
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Yavari, Issa, et al. “Solvent-free synthesis of functionalized 5-imino-2,5-dihydrofurans from isocyanides, activated acetylenes and alkyl cyanoformates.” Mendeleev Communications, vol. 21, no. 4, Jul. 2011, pp. 229-230. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.020.

Abstract

The reaction between alkyl(aryl) isocyanides, dialkyl acetylenedicarboxylates and alkyl cyanoformates under solvent-free conditions leads to dialkyl 2-cyano-5-alkyl(aryl)imino-2-alkoxy-2,5-dihydrofuran-3,4-dicarboxylates in high yields.

References

1.
Small ring systems from isocyanides. I. Reaction of isocyanides with hexafluorobutyne-2
Oakes T.R., David H.G., Nagel F.J.
Journal of the American Chemical Society, 1969
2.
Reactions of isocyanides with activated acetylenes in protic solvents
Oakes T.R., Donovan D.J.
Journal of Organic Chemistry, 1973
3.
A facile route to highly functionalized ketenimines
Yavari I., Davar-Panah M., Heydari M., Najafian K., Zonouzi A.
Monatshefte fur Chemie, 1996
11.
One-Pot Synthesis of 4-Hydroxy-3-phenyl-2H-pyrano[3,2-b]benzofuran-2-one Derivatives
Foroumadi A., Zamanian S., Samzadeh-Kermani A., Shafiee A.
Synthetic Communications, 2009