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Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation

Lyudmila Yur'evna Alikberova 1
Lyudmila Yur'evna Alikberova
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Nataliya Samuilovna Rukk 1
Nataliya Samuilovna Rukk
, 
10.1016/j.mencom.2011.07.011
Published 2011-07-01
Communication , Volume 21, Issue 4, 204-205
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Alikberova L. Y. et al. Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation // Mendeleev Communications. 2011. Vol. 21. No. 4. pp. 204-205.
GOST all authors (up to 50) Copy
Alikberova L. Y., Lyssenko K. A., Rukk N. S., Mytareva A. I. Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation // Mendeleev Communications. 2011. Vol. 21. No. 4. pp. 204-205.
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TY - JOUR
DO - 10.1016/j.mencom.2011.07.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.011
TI - Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation
T2 - Mendeleev Communications
AU - Alikberova, Lyudmila Yur'evna
AU - Lyssenko, Konstantin Alexandrovich
AU - Rukk, Nataliya Samuilovna
AU - Mytareva, Alina Igorevna
PY - 2011
DA - 2011/07/01
PB - Mendeleev Communications
SP - 204-205
IS - 4
VL - 21
ER -
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@article{2011_Alikberova,
author = {Lyudmila Yur'evna Alikberova and Konstantin Alexandrovich Lyssenko and Nataliya Samuilovna Rukk and Alina Igorevna Mytareva},
title = {Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.011},
number = {4},
pages = {204--205},
doi = {10.1016/j.mencom.2011.07.011}
}
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Alikberova, Lyudmila Yur'evna, et al. “Carbamide-containing complexes of lanthanides: competition of hydrogen bonding and polyiodide ion formation.” Mendeleev Communications, vol. 21, no. 4, Jul. 2011, pp. 204-205. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.07.011.

Abstract

The carbamide complexes of lanthanide polyiodoiodates [Tm(ur)7][I3]3·2I2, [Yb(ur)6][I3]3 and [Lu(ur)6][I3]3 [ur is O=C(NH2)2] have been synthesized and structurally characterized. The structure-forming role of the pentaiodide ions taking part in the formation of extended channels 10–12Å in diameter with incorporated hepta(carbamide)thulium cations combined to one another into infinite columns due to H-bonding, or the triiodide ions forming lace-like net with isolated hexa(carbamide)ytterbium(iii) or hexa(carbamide) lutetium(iii) cations located in the net holes has been revealed.

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