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Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes

Lidia Nikolaevna Pankratova 1
Lidia Nikolaevna Pankratova
,  , 
Vladislav l Bugaenko 2
Vladislav l Bugaenko
, 
Valentin Vasil'evich Makhlyarchuk 3
Valentin Vasil'evich Makhlyarchuk
10.1016/j.mencom.2011.04.016
Published 2011-04-28
Communication , Volume 21, Issue 3, 157-159
6
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Pankratova L. N. et al. Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 157-159.
GOST all authors (up to 50) Copy
Pankratova L. N., Saenko E. V., Bugaenko V. L., Makhlyarchuk V. V. Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 157-159.
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TY - JOUR
DO - 10.1016/j.mencom.2011.04.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.016
TI - Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes
T2 - Mendeleev Communications
AU - Pankratova, Lidia Nikolaevna
AU - Saenko, Elizaveta Vladimirovna
AU - Bugaenko, Vladislav l
AU - Makhlyarchuk, Valentin Vasil'evich
PY - 2011
DA - 2011/04/28
PB - Mendeleev Communications
SP - 157-159
IS - 3
VL - 21
ER -
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@article{2011_Pankratova,
author = {Lidia Nikolaevna Pankratova and Elizaveta Vladimirovna Saenko and Vladislav l Bugaenko and Valentin Vasil'evich Makhlyarchuk},
title = {Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.016},
number = {3},
pages = {157--159},
doi = {10.1016/j.mencom.2011.04.016}
}
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Pankratova, Lidia Nikolaevna, et al. “Kinetics of decay of methyl radicals in irradiated dimethylsilanediol and polymethylsiloxanes.” Mendeleev Communications, vol. 21, no. 3, Apr. 2011, pp. 157-159. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.016.

Abstract

As found by EPR spectroscopy, the decay of methyl radicals in the test compounds upon X-ray irradiation at 77K resulted from radical-center transfer rather than radical combination; the rate constants of decay of methyl radicals in polydimethylsiloxane and its structural analog dimethylsilanediol were almost the same.

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