Home / Publications / Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals

Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals

Oleg Vyacheslavovich Maltsev 1, 2
Oleg Vyacheslavovich Maltsev
, 
Alexander Sergeevich Kucherenko 1
Alexander Sergeevich Kucherenko
, 
Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
10.1016/j.mencom.2011.04.011
Published 2011-04-28
Communication , Volume 21, Issue 3, 146-148
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Maltsev O. V., Kucherenko A. S., Zlotin S. G. Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 146-148.
GOST all authors (up to 50) Copy
Maltsev O. V., Kucherenko A. S., Zlotin S. G. Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 146-148.
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TY - JOUR
DO - 10.1016/j.mencom.2011.04.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.011
TI - Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals
T2 - Mendeleev Communications
AU - Maltsev, Oleg Vyacheslavovich
AU - Kucherenko, Alexander Sergeevich
AU - Zlotin, Sergei Grigorievich
PY - 2011
DA - 2011/04/28
PB - Mendeleev Communications
SP - 146-148
IS - 3
VL - 21
ER -
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@article{2011_Maltsev,
author = {Oleg Vyacheslavovich Maltsev and Alexander Sergeevich Kucherenko and Sergei Grigorievich Zlotin},
title = {Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.011},
number = {3},
pages = {146--148},
doi = {10.1016/j.mencom.2011.04.011}
}
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Maltsev, Oleg Vyacheslavovich, et al. “Ionic polymer-supported O-trimethylsilyl-α,α-diphenyl-(S)-prolinols as recoverable organocatalysts for the asymmetric Michael reactions of carbon acids with α,β-enals.” Mendeleev Communications, vol. 21, no. 3, Apr. 2011, pp. 146-148. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.011.

Abstract

A recyclable organocatalyst bearing O-trimethylsilyl-α,α-diphenyl-(S)-prolinol unit tagged to the imidazolium cation and poly(4-styrenesulfonate) anion in the reaction of CH-acids with α,β-enals provided the respective Michael adducts in high yields (up to 99%) and with high enantioselectivities (up to 98% ee).

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