Home / Publications / An expedient synthesis of diethyl diazomethylphosphonate

An expedient synthesis of diethyl diazomethylphosphonate

Mikhail Dmitrievich Kosobokov 1
Mikhail Dmitrievich Kosobokov
, 
Igor Dem'yanovich Titanyuk 1
Igor Dem'yanovich Titanyuk
, 
10.1016/j.mencom.2011.04.009
Published 2011-04-28
Communication , Volume 21, Issue 3, 142-143
7
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kosobokov M. D., Titanyuk I. D., Beletskaya I. P. An expedient synthesis of diethyl diazomethylphosphonate // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 142-143.
GOST all authors (up to 50) Copy
Kosobokov M. D., Titanyuk I. D., Beletskaya I. P. An expedient synthesis of diethyl diazomethylphosphonate // Mendeleev Communications. 2011. Vol. 21. No. 3. pp. 142-143.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2011.04.009
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.009
TI - An expedient synthesis of diethyl diazomethylphosphonate
T2 - Mendeleev Communications
AU - Kosobokov, Mikhail Dmitrievich
AU - Titanyuk, Igor Dem'yanovich
AU - Beletskaya, Irina Petrovna
PY - 2011
DA - 2011/04/28
PB - Mendeleev Communications
SP - 142-143
IS - 3
VL - 21
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Kosobokov,
author = {Mikhail Dmitrievich Kosobokov and Igor Dem'yanovich Titanyuk and Irina Petrovna Beletskaya},
title = {An expedient synthesis of diethyl diazomethylphosphonate},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.009},
number = {3},
pages = {142--143},
doi = {10.1016/j.mencom.2011.04.009}
}
MLA
Cite this
MLA Copy
Kosobokov, Mikhail Dmitrievich, et al. “An expedient synthesis of diethyl diazomethylphosphonate.” Mendeleev Communications, vol. 21, no. 3, Apr. 2011, pp. 142-143. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.04.009.

Abstract

A simple three-step preparation of diethyl diazomethylphosphonate was performed from chloroacetone and triethyl phosphite in total yield 70%.

References

1.
F. Heaney, in Comprehensive Organic Functional Group Transformations, eds. A. R. Katritzky, O. Meth-Kohn and C. W. Rees, Elsevier, Oxford, 1995, vol. 4, ch. 4, p. 10.
2.
10.1016/j.mencom.2011.04.009_bib0010
Filler
Organofluorine Compounds in Medicinal Chemistry and Biomedicinal Applications, 1999
6.
The reaction of dimethyl dioxirane with diazomethylphosphonates; the first synthesis of a formylphosphonate hydrate
Hamilton R., McKervey M.A., Rafferty M.D., Walker B.J.
Journal of the Chemical Society Chemical Communications, 1994
7.
Phosphonylated thiocarbonyl ylides from the reaction of aromatic thioketones with diethyl diazomethylphosphonates
Lesniak S., Mloston G., Urbaniak K., Wasiak P., Linden A., Heimgartner H.
Tetrahedron, 2006
8.
A simple procedure for the elaboration of carbonyl compounds into homologous alkynes
Colvin E.W., Hamill B.J.
Journal of the Chemical Society Perkin Transactions 1, 1977
11.
Asymmetric Hydrogenation of .beta.-Keto Phosphonates: A Practical Way to Fosfomycin
Kitamura M., Tokunaga M., Noyori R.
Journal of the American Chemical Society, 1995
12.
10.1016/j.mencom.2011.04.009_bib0055
Regitz
Org. Synth., 1973