Home / Publications / Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+

Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+

, 
Èduard Èduardovich Karslyan 1
Èduard Èduardovich Karslyan
, 
Alexandra Olegovna Borissova 1
Alexandra Olegovna Borissova
, 
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
10.1016/j.mencom.2011.03.007
Published 2011-03-10
Communication , Volume 21, Issue 2, 82-83
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Perekalin D. S. et al. Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+ // Mendeleev Communications. 2011. Vol. 21. No. 2. pp. 82-83.
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Perekalin D. S., Karslyan È. È., Borissova A. O., Kudinov A. R. Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+ // Mendeleev Communications. 2011. Vol. 21. No. 2. pp. 82-83.
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TY - JOUR
DO - 10.1016/j.mencom.2011.03.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.03.007
TI - Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+
T2 - Mendeleev Communications
AU - Perekalin, Dmitrii Sergeevich
AU - Karslyan, Èduard Èduardovich
AU - Borissova, Alexandra Olegovna
AU - Kudinov, Alexander Rudolfovich
PY - 2011
DA - 2011/03/10
PB - Mendeleev Communications
SP - 82-83
IS - 2
VL - 21
ER -
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@article{2011_Perekalin,
author = {Dmitrii Sergeevich Perekalin and Èduard Èduardovich Karslyan and Alexandra Olegovna Borissova and Alexander Rudolfovich Kudinov},
title = {Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.03.007},
number = {2},
pages = {82--83},
doi = {10.1016/j.mencom.2011.03.007}
}
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Perekalin, Dmitrii Sergeevich, et al. “Convenient synthesis of the ruthenium complexes CpRu(diene)X (X=Cl, Br, I) by naphthalene substitution in [CpRu(C10H8)]+.” Mendeleev Communications, vol. 21, no. 2, Mar. 2011, pp. 82-83. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.03.007.

Abstract

The replacement of naphthalene ligand in the ruthenium complex [CpRu(C10H8)]+ by halide anions in the presence of 1,5-cyclooctadiene (cod) or norbornadiene (nbd) gives important synthetic precursors CpRu(cod)X and CpRu(nbd)X (X=Cl, Br, I) in 60–90% yield; the structure of CpRu(nbd)Br was determined by X-ray diffraction.

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