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Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives

Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Svetlana Il'yasovna Verkhoturova 1
Svetlana Il'yasovna Verkhoturova
, 
Tatyana Ivanovna Kazantseva 1
Tatyana Ivanovna Kazantseva
, 
Valentina L'vovna Mikhailenko 1
Valentina L'vovna Mikhailenko
, 
Svetlana Nikolaevna Arbuzova 1
Svetlana Nikolaevna Arbuzova
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1016/j.mencom.2011.01.007
Published 2011-01-12
Communication , Volume 21, Issue 1, 17-18
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Gusarova N. K. et al. Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives // Mendeleev Communications. 2011. Vol. 21. No. 1. pp. 17-18.
GOST all authors (up to 50) Copy
Gusarova N. K., Verkhoturova S. I., Kazantseva T. I., Mikhailenko V. L., Arbuzova S. N., Trofimov B. A. Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives // Mendeleev Communications. 2011. Vol. 21. No. 1. pp. 17-18.
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TY - JOUR
DO - 10.1016/j.mencom.2011.01.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.01.007
TI - Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives
T2 - Mendeleev Communications
AU - Gusarova, Nina Kuzminichna
AU - Verkhoturova, Svetlana Il'yasovna
AU - Kazantseva, Tatyana Ivanovna
AU - Mikhailenko, Valentina L'vovna
AU - Arbuzova, Svetlana Nikolaevna
AU - Trofimov, Boris Aleksandrovich
PY - 2011
DA - 2011/01/12
PB - Mendeleev Communications
SP - 17-18
IS - 1
VL - 21
ER -
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@article{2011_Gusarova,
author = {Nina Kuzminichna Gusarova and Svetlana Il'yasovna Verkhoturova and Tatyana Ivanovna Kazantseva and Valentina L'vovna Mikhailenko and Svetlana Nikolaevna Arbuzova and Boris Aleksandrovich Trofimov},
title = {Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives},
journal = {Mendeleev Communications},
year = {2011},
volume = {21},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.01.007},
number = {1},
pages = {17--18},
doi = {10.1016/j.mencom.2011.01.007}
}
MLA
Cite this
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Gusarova, Nina Kuzminichna, et al. “Free-radical addition of phosphine to vinyl ethers: atom-economic synthesis of tris(2-organyloxyethyl)phosphines and their derivatives.” Mendeleev Communications, vol. 21, no. 1, Jan. 2011, pp. 17-18. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2011.01.007.

Abstract

Phosphine, generated from red phosphorus in the system KOH–H2O–toluene, reacts with vinyl ethers under radical initiation (AIBN, dioxane, 78–80°C, atmospheric pressure) to give tris(2-organyloxyethyl)phosphines, which are transformed to the corresponding phosphine chalcogenides (in up to 73% isolated yield) via the reactions with air oxygen, elemental sulfur or selenium.

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