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The first example of the Schmidt reaction in ionic liquids

Margarita Alekseevna Epishina 1
Margarita Alekseevna Epishina
Alexander Sergeyevich Kulikov 1
Alexander Sergeyevich Kulikov
Nikolai V Ignat'ev 2
Nikolai V Ignat'ev
Michael Schulte 2
Michael Schulte
Nina Nikolaevna Makhova 1
Nina Nikolaevna Makhova
2 Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany
Published 2010-11-02
CommunicationVolume 20, Issue 6, 335-336
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Epishina M. A. et al. The first example of the Schmidt reaction in ionic liquids // Mendeleev Communications. 2010. Vol. 20. No. 6. pp. 335-336.
GOST all authors (up to 50) Copy
Epishina M. A., Kulikov A. S., Ignat'ev N. V., Schulte M., Makhova N. N. The first example of the Schmidt reaction in ionic liquids // Mendeleev Communications. 2010. Vol. 20. No. 6. pp. 335-336.
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TY - JOUR
DO - 10.1016/j.mencom.2010.11.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.11.011
TI - The first example of the Schmidt reaction in ionic liquids
T2 - Mendeleev Communications
AU - Epishina, Margarita Alekseevna
AU - Kulikov, Alexander Sergeyevich
AU - Ignat'ev, Nikolai V
AU - Schulte, Michael
AU - Makhova, Nina Nikolaevna
PY - 2010
DA - 2010/11/02
PB - Mendeleev Communications
SP - 335-336
IS - 6
VL - 20
ER -
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@article{2010_Epishina,
author = {Margarita Alekseevna Epishina and Alexander Sergeyevich Kulikov and Nikolai V Ignat'ev and Michael Schulte and Nina Nikolaevna Makhova},
title = {The first example of the Schmidt reaction in ionic liquids},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.11.011},
number = {6},
pages = {335--336},
doi = {10.1016/j.mencom.2010.11.011}
}
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Epishina, Margarita Alekseevna, et al. “The first example of the Schmidt reaction in ionic liquids.” Mendeleev Communications, vol. 20, no. 6, Nov. 2010, pp. 335-336. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.11.011.

Abstract

The Schmidt reaction of aryl methyl ketones in ionic liquids (optimally in 1-ethyl-3-methylimidazolium triflate with CF3SO3H additive) proceeds at 40°C within 10–30 h to give the corresponding acetanilides in good yields.

References

1.
The Effect of Structure on the Course of the Schmidt Reaction on Unsymmetrical Ketones1
Smith P.A., Horwitz J.P.
Journal of the American Chemical Society, 1950
2.
10.1016/j.mencom.2010.11.011_bib0010
Li
Heidelberg, 2003
7.
Synthesis of methyl orange using ionic liquids
Astolfi D.L., Mayville F.C.
Tetrahedron Letters, 2003
11.
Syntheses of All Isomers of Naphthalenetricarboxylic Acids
Dozen Y.
Bulletin of the Chemical Society of Japan, 1972
13.
Additionsreaktionen der nitrosogruppe—XV
18.
Distribution of Tritiated Derivatives of Fluorene in the Rat
Ray F.E., Wejebe O.O.
Journal of Pharmaceutical Sciences, 1964