Home / Publications / [(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization

[(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization

Vadim Vladimirovich Popov 1
Vadim Vladimirovich Popov
, 
Stanislav Anatol'evich Amelichev 1
Stanislav Anatol'evich Amelichev
, 
Lidia Sergeevna Konstantinova 1
Lidia Sergeevna Konstantinova
, 
Ivan Vladimirovich Glukhov 2
Ivan Vladimirovich Glukhov
, 
Konstantin Alexandrovich Lyssenko 2
Konstantin Alexandrovich Lyssenko
, 
Oleg Alexeevich Rakitin 1
Oleg Alexeevich Rakitin
10.1016/j.mencom.2010.09.014
Published 2010-09-09
Communication , Volume 20, Issue 5, 279-281
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Popov V. V. et al. [(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization // Mendeleev Communications. 2010. Vol. 20. No. 5. pp. 279-281.
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Popov V. V., Amelichev S. A., Konstantinova L. S., Glukhov I. V., Lyssenko K. A., Rakitin O. A. [(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization // Mendeleev Communications. 2010. Vol. 20. No. 5. pp. 279-281.
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TY - JOUR
DO - 10.1016/j.mencom.2010.09.014
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.014
TI - [(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization
T2 - Mendeleev Communications
AU - Popov, Vadim Vladimirovich
AU - Amelichev, Stanislav Anatol'evich
AU - Konstantinova, Lidia Sergeevna
AU - Glukhov, Ivan Vladimirovich
AU - Lyssenko, Konstantin Alexandrovich
AU - Rakitin, Oleg Alexeevich
PY - 2010
DA - 2010/09/09
PB - Mendeleev Communications
SP - 279-281
IS - 5
VL - 20
ER -
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@article{2010_Popov,
author = {Vadim Vladimirovich Popov and Stanislav Anatol'evich Amelichev and Lidia Sergeevna Konstantinova and Ivan Vladimirovich Glukhov and Konstantin Alexandrovich Lyssenko and Oleg Alexeevich Rakitin},
title = {[(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.014},
number = {5},
pages = {279--281},
doi = {10.1016/j.mencom.2010.09.014}
}
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Popov, Vadim Vladimirovich, et al. “[(4-Sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formic acid derivatives: synthesis from 5-oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride and structural characterization.” Mendeleev Communications, vol. 20, no. 5, Sep. 2010, pp. 279-281. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.014.

Keywords

1,3-dithioles
1,3,2-dithiazoles
alcohols
amines
synthesis
X-ray diffraction

Abstract

5-Oxo[1,3]dithiolo[4,5-d][1,3,2]dithiazol-1-ium chloride was converted into [(4-sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]-formic acid esters and amides upon treatment with alcohols and amines, respectively; the structure of propyl [(4-sulfanylidene-4H-1λ4,3,2-dithiazol-5-yl)sulfanyl]formate was confirmed by X-ray diffraction.

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