Home / Publications / Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4

Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4

Dmitry Alexandrovich Loginov 1
Dmitry Alexandrovich Loginov
Andrey Anatol'evich Pronin 1
Andrey Anatol'evich Pronin
Zoya Aleksandrovna Starikova 1
Zoya Aleksandrovna Starikova
Pavel Vasil'evich Petrovskii 1
Pavel Vasil'evich Petrovskii
Alexander Rudolfovich Kudinov 1
Alexander Rudolfovich Kudinov
Published 2010-09-09
CommunicationVolume 20, Issue 5, 271-272
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Loginov D. A. et al. Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4 // Mendeleev Communications. 2010. Vol. 20. No. 5. pp. 271-272.
GOST all authors (up to 50) Copy
Loginov D. A., Pronin A. A., Starikova Z. A., Petrovskii P. V., Kudinov A. R. Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4 // Mendeleev Communications. 2010. Vol. 20. No. 5. pp. 271-272.
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TY - JOUR
DO - 10.1016/j.mencom.2010.09.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.010
TI - Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4
T2 - Mendeleev Communications
AU - Loginov, Dmitry Alexandrovich
AU - Pronin, Andrey Anatol'evich
AU - Starikova, Zoya Aleksandrovna
AU - Petrovskii, Pavel Vasil'evich
AU - Kudinov, Alexander Rudolfovich
PY - 2010
DA - 2010/09/09
PB - Mendeleev Communications
SP - 271-272
IS - 5
VL - 20
ER -
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@article{2010_Loginov,
author = {Dmitry Alexandrovich Loginov and Andrey Anatol'evich Pronin and Zoya Aleksandrovna Starikova and Pavel Vasil'evich Petrovskii and Alexander Rudolfovich Kudinov},
title = {Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.010},
number = {5},
pages = {271--272},
doi = {10.1016/j.mencom.2010.09.010}
}
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Loginov, Dmitry Alexandrovich, et al. “Photochemical arene exchange in the (borole)cobalt complex [(η-C4H4BOH)Co(η-C6H6)]BF4.” Mendeleev Communications, vol. 20, no. 5, Sep. 2010, pp. 271-272. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.09.010.

Abstract

Visible-light irradiation of the cation [(η-C4H4BOH)Co(η-C6H6)]+ in the presence of alkyl-substituted benzenes in CH2Cl2 results in arene exchange giving [(η-C4H4BOH)Co(η-C6R6)]+ (C6R6= toluene, p-xylene or mesitylene); the structure of [(η-C4H4BOH)Co(η-mesitylene)]BF4 was confirmed by X-ray diffraction.

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