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Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18

Nadezhda Borisovna Tamm 1
Nadezhda Borisovna Tamm
, 
10.1016/j.mencom.2010.06.016
Published 2010-06-16
Communication , Volume 20, Issue 4, 229-230
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Tamm N. B., Troyanov S. I. Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18 // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 229-230.
GOST all authors (up to 50) Copy
Tamm N. B., Troyanov S. I. Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18 // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 229-230.
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TY - JOUR
DO - 10.1016/j.mencom.2010.06.016
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.016
TI - Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18
T2 - Mendeleev Communications
AU - Tamm, Nadezhda Borisovna
AU - Troyanov, Sergey Igorevich
PY - 2010
DA - 2010/06/16
PB - Mendeleev Communications
SP - 229-230
IS - 4
VL - 20
ER -
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@article{2010_Tamm,
author = {Nadezhda Borisovna Tamm and Sergey Igorevich Troyanov},
title = {Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.016},
number = {4},
pages = {229--230},
doi = {10.1016/j.mencom.2010.06.016}
}
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Tamm, Nadezhda Borisovna, and Sergey Igorevich Troyanov. “Trifluoromethyl derivatives of fullerene C76, C76(CF3)14–18.” Mendeleev Communications, vol. 20, no. 4, Jun. 2010, pp. 229-230. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.016.

Abstract

The trifluoromethylation of a higher fullerene mixture followed by the HPLC separation of CF3 derivatives resulted in the isolation of C76(CF3)14, C76(CF3)16 and C76(CF3)18 (two isomers), the crystal and molecular structures of which were determined by X-ray diffraction with the use of synchrotron radiation.

References

1.
P.W. Fowler and D. E.Manolopoulos, An Atlas of Fullerenes, Clarendon, Oxford, 1995, p. 392.
2.
Isolation of C76, a chiral (D2) allotrope of carbon
Ettl R., Chao I., Diederich F., Whetten R.L.
Nature, 1991
3.
Connectivity of the ChiralD2-Symmetric Isomer of C76 through a Crystal-Structure Determination of C76Cl18⋅TiCl4
Simeonov K., Amsharov K., Jansen M.
Angewandte Chemie - International Edition, 2007
4.
C76Cl34: High Chlorination of the Inherent Chiral Fullerene with a Helical Configuration
Liang H., Tan Y., Zhou T., Chen Z., Xie S., Huang R., Zheng L.
Inorganic Chemistry, 2010
5.
Synthesis and X-ray or NMR/DFT Structure Elucidation of Twenty-One New Trifluoromethyl Derivatives of Soluble Cage Isomers of C76, C78, C84, and C90
Kareev I.E., Popov A.A., Kuvychko I.V., Shustova N.B., Lebedkin S.F., Bubnov V.P., Anderson O.P., Seppelt K., Strauss S.H., Boltalina O.V.
Journal of the American Chemical Society, 2008
6.
Fusing Pentagons in a Fullerene Cage by Chlorination: IPRD2-C76Rearranges into non-IPR C76Cl24
Ioffe I., Goryunkov A., Tamm N., Sidorov L., Kemnitz E., Troyanov S.
Angewandte Chemie - International Edition, 2009
7.
A short history of SHELX
Sheldrick G.M.
Acta Crystallographica Section A Foundations of Crystallography, 2007
8.
Isolation and Structural X-ray Investigation of Perfluoroalkyl Derivatives of Six Cage Isomers of C84
Tamm N.B., Sidorov L., Kemnitz E., Troyanov S.
Chemistry - A European Journal, 2009
9.
10.1016/j.mencom.2010.06.016_bib8
Troyanov
Kristallografiya, 2009
10.
10.1016/j.mencom.2010.06.016_bib9
Tamm
Chem. Commun., 2009
11.
Synthesis and structural characterization of highly chlorinated C70, C70Cl28.
Troyanov S.I., Shustova N.B., Ioffe I.N., Turnbull A.P., Kemnitz E.
Chemical Communications, 2005
12.
C2 C70F38 is aromatic, contains three planar hexagons, and has equatorial addends.
Hitchcock P.B., Avent A.G., Martsinovich N., Troshin P.A., Taylor R.
Chemical Communications, 2005
13.
C1 C70F38 contains four planar aromatic hexagons; the parallel between fluorination of [60]- and [70]fullerenes.
Hitchcock P.B., Avent A.G., Martsinovich N., Troshin P.A., Taylor R.
Organic Letters, 2005
15.
10.1016/j.mencom.2010.06.016_bib14
Ignat’eva
Izv. Akad. Nauk, Ser. Khim., 2009
16.
X-ray structure and DFT study of C1-C60(CF3)12. A high-energy, kinetically-stable isomer prepared at 500 °C
Kareev I.E., Shustova N.B., Peryshkov D.V., Lebedkin S.F., Miller S.M., Anderson O.P., Popov A.A., Boltalina O.V., Strauss S.H.
Chemical Communications, 2007