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Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation

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Vladimir Isaevich Feldman 1, 2
Vladimir Isaevich Feldman
10.1016/j.mencom.2010.06.007
Published 2010-06-16
Communication , Volume 20, Issue 4, 205-206
4
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Tyurin D. A., Shiryaeva E. S., Feldman V. I. Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 205-206.
GOST all authors (up to 50) Copy
Tyurin D. A., Shiryaeva E. S., Feldman V. I. Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 205-206.
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TY - JOUR
DO - 10.1016/j.mencom.2010.06.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.007
TI - Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation
T2 - Mendeleev Communications
AU - Tyurin, Daniil Aleksandrovich
AU - Shiryaeva, Ekaterina Sergeevna
AU - Feldman, Vladimir Isaevich
PY - 2010
DA - 2010/06/16
PB - Mendeleev Communications
SP - 205-206
IS - 4
VL - 20
ER -
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@article{2010_Tyurin,
author = {Daniil Aleksandrovich Tyurin and Ekaterina Sergeevna Shiryaeva and Vladimir Isaevich Feldman},
title = {Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.007},
number = {4},
pages = {205--206},
doi = {10.1016/j.mencom.2010.06.007}
}
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Tyurin, Daniil Aleksandrovich, et al. “Structure and photochemical rearrangement of the 3,3-dimethylbut-1-yne radical cation.” Mendeleev Communications, vol. 20, no. 4, Jun. 2010, pp. 205-206. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.007.

Keywords

EPR
low-temperature matrices
radical cations

Abstract

The structure of the 3,3-dimethylbut-1-yne radical cation and its unusual photochemical rearrangement to the trimethylallene radical cation have been characterized by low-temperature matrix EPR spectroscopy and DFT calculations.

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