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Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium

Alex R Petrov 1
Alex R Petrov
, 
Konstantin Alexandrovich Rufanov 2
Konstantin Alexandrovich Rufanov
, 
Noa K Hangaly 1
Noa K Hangaly
, 
Michael Elfferding 1
Michael Elfferding
, 
Klaus Harms 1
Klaus Harms
, 
Jorg Sundermeyer 1
Jorg Sundermeyer
2 Department of Organic Chemistry, Chemical Diversity Research Institute, Khimki, Moscow Region, Russian Federation
10.1016/j.mencom.2010.06.004
Published 2010-06-16
Communication , Volume 20, Issue 4, 197-199
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Petrov A. R. et al. Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 197-199.
GOST all authors (up to 50) Copy
Petrov A. R., Rufanov K. A., Hangaly N. K., Elfferding M., Harms K., Sundermeyer J. Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium // Mendeleev Communications. 2010. Vol. 20. No. 4. pp. 197-199.
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TY - JOUR
DO - 10.1016/j.mencom.2010.06.004
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.004
TI - Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium
T2 - Mendeleev Communications
AU - Petrov, Alex R
AU - Rufanov, Konstantin Alexandrovich
AU - Hangaly, Noa K
AU - Elfferding, Michael
AU - Harms, Klaus
AU - Sundermeyer, Jorg
PY - 2010
DA - 2010/06/16
PB - Mendeleev Communications
SP - 197-199
IS - 4
VL - 20
ER -
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@article{2010_Petrov,
author = {Alex R Petrov and Konstantin Alexandrovich Rufanov and Noa K Hangaly and Michael Elfferding and Klaus Harms and Jorg Sundermeyer},
title = {Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.004},
number = {4},
pages = {197--199},
doi = {10.1016/j.mencom.2010.06.004}
}
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MLA Copy
Petrov, Alex R., et al. “Air-stable helical bis(cyclopentadienylphosphazene) complexes of divalent ytterbium.” Mendeleev Communications, vol. 20, no. 4, Jun. 2010, pp. 197-199. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.06.004.

Keywords

constrained geometry complexes
cyclopentadienyl-phosphazene ligand
divalent ytterbium
oxidative stable
Staudinger reaction

Abstract

Two homoleptic YbII constrained geometry complexes [Yb{η5,η1-R2P(C5Me4)NAd}2] [R =Me (3), Ph (4); Ad=1-adamantyl] derived from P-amino(cyclopentadienylidene)phosphoranes (CpPN) R2P(C5Me4)NHAd [R=Me (1), Ph (2)] were found to be remarkably stable towards dioxygen, as shown by NMR spectroscopy and further confirmed by the crystal structure analysis of 4 and discussed in terms of efficient steric shielding and electronic stabilization of the YbII metal centre by this CpPN ligand type.

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