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Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands

Dmitrii Ilyich D'yachikhin ¹

Dmitrii Ilyich D'yachikhin

Fedor Mikhailovich Dolgushin ¹

Fedor Mikhailovich Dolgushin

Ivan Alexandrovich Godovikov ¹

Ivan Alexandrovich Godovikov

Igor Timofeevich Chizhevsky ¹

Igor Timofeevich Chizhevsky

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

10.1016/j.mencom.2010.05.018

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Published 2010-05-06

Communication , Volume 20, Issue 3, 174-176

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D'yachikhin D. I. et al. Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands // Mendeleev Communications. 2010. Vol. 20. No. 3. pp. 174-176.

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D'yachikhin D. I., Dolgushin F. M., Godovikov I. A., Chizhevsky I. T. Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands // Mendeleev Communications. 2010. Vol. 20. No. 3. pp. 174-176.

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TY - JOUR

DO - 10.1016/j.mencom.2010.05.018

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.018

TI - Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands

T2 - Mendeleev Communications

AU - D'yachikhin, Dmitrii Ilyich

AU - Dolgushin, Fedor Mikhailovich

AU - Godovikov, Ivan Alexandrovich

AU - Chizhevsky, Igor Timofeevich

PY - 2010

DA - 2010/05/06

PB - Mendeleev Communications

SP - 174-176

IS - 3

VL - 20

ER -

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@article{2010_D'yachikhin,

author = {Dmitrii Ilyich D'yachikhin and Fedor Mikhailovich Dolgushin and Ivan Alexandrovich Godovikov and Igor Timofeevich Chizhevsky},

title = {Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands},

journal = {Mendeleev Communications},

year = {2010},

volume = {20},

publisher = {Mendeleev Communications},

month = {May},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.018},

number = {3},

pages = {174--176},

doi = {10.1016/j.mencom.2010.05.018}

}

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D'yachikhin, Dmitrii Ilyich, et al. “Ligand-displacement reactions as a powerful route to closo-ruthenacarboranes incorporating bidentate N-donor ligands.” Mendeleev Communications, vol. 20, no. 3, May. 2010, pp. 174-176. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.018.

Abstract

A facile ligand-exchange method based on the direct reaction of either three-bridge exo-nido complex [exo-5,6,10-{Cl(Ph₃P)₂Ru}- 5,6,10-(μ-H)₃-10-H-nido-7,8-C₂B₉H₈] or its closo isomer [3,3-(PPh₃)₂-3-Cl-3-H-3,1,2-closo-RuC₂B₉H₁₁] with chelating N,N-donor ligands was employed to synthesize the N,N-diamine-closo-ruthenacarborane complexes [3,3-{κ²-4,4’-R₂-2,2’-(C₅H₃N)₂}-3-PPh₃-closo-3,1,2-RuC₂B₉H₁₁] (R=H, Bu^t) and [3,3-{κ²-phen}-3-PPh₃-closo-3,1,2-RuC₂B₉H₁₁].

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