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Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands

Sergey Evgen'evich Lyubimov 1
Sergey Evgen'evich Lyubimov
, 
Ilya Vladimirovich Kuchurov 2
Ilya Vladimirovich Kuchurov
, 
Andrei Alexandrovich Vasil'ev 2
Andrei Alexandrovich Vasil'ev
, 
Sergei Grigorievich Zlotin 2
Sergei Grigorievich Zlotin
, 
Vadim Alexandrovich Davankov 1
Vadim Alexandrovich Davankov
10.1016/j.mencom.2010.05.006
Published 2010-05-06
Communication , Volume 20, Issue 3, 143-144
10
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Lyubimov S. E. et al. Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands // Mendeleev Communications. 2010. Vol. 20. No. 3. pp. 143-144.
GOST all authors (up to 50) Copy
Lyubimov S. E., Kuchurov I. V., Vasil'ev A. A., Zlotin S. G., Davankov V. A. Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands // Mendeleev Communications. 2010. Vol. 20. No. 3. pp. 143-144.
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TY - JOUR
DO - 10.1016/j.mencom.2010.05.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.006
TI - Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands
T2 - Mendeleev Communications
AU - Lyubimov, Sergey Evgen'evich
AU - Kuchurov, Ilya Vladimirovich
AU - Vasil'ev, Andrei Alexandrovich
AU - Zlotin, Sergei Grigorievich
AU - Davankov, Vadim Alexandrovich
PY - 2010
DA - 2010/05/06
PB - Mendeleev Communications
SP - 143-144
IS - 3
VL - 20
ER -
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@article{2010_Lyubimov,
author = {Sergey Evgen'evich Lyubimov and Ilya Vladimirovich Kuchurov and Andrei Alexandrovich Vasil'ev and Sergei Grigorievich Zlotin and Vadim Alexandrovich Davankov},
title = {Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.006},
number = {3},
pages = {143--144},
doi = {10.1016/j.mencom.2010.05.006}
}
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Lyubimov, Sergey Evgen'evich, et al. “Asymmetric allylic alkylation in supercritical carbon dioxide using P*-chiral diamidophosphite ligands.” Mendeleev Communications, vol. 20, no. 3, May. 2010, pp. 143-144. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.05.006.

Abstract

P*-Chiral diamidophosphite ligands in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate in supercritical carbon dioxide provide enantioselectivities up to 90% ee. The catalytic performance is affected greatly by temperature, CO2 pressures and structure of catalysts.

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