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A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids

Andrey Grigorievich Vendilo 1
Andrey Grigorievich Vendilo
, 
Dmitry Ivanovich Djigailo 2
Dmitry Ivanovich Djigailo
, 
Hannu Rönkkömäki 3
Hannu Rönkkömäki
, 
Marja Lajunen 4
Marja Lajunen
, 
Elena Aleksandrovna Chernikova 5
Elena Aleksandrovna Chernikova
, 
Lauri H.J. Lajunen 4
Lauri H.J. Lajunen
, 
Igor Vladimirovich Pletnev 2
Igor Vladimirovich Pletnev
, 
Konstantin Ivanovich Popov 1, 4, 6
Konstantin Ivanovich Popov
10.1016/j.mencom.2010.03.020
Published 2010-03-05
Communication , Volume 20, Issue 2, 122-124
12
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Vendilo A. G. et al. A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids // Mendeleev Communications. 2010. Vol. 20. No. 2. pp. 122-124.
GOST all authors (up to 50) Copy
Vendilo A. G., Djigailo D. I., Rönkkömäki H., Lajunen M., Chernikova E. A., Lajunen L. H., Pletnev I. V., Popov K. I. A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids // Mendeleev Communications. 2010. Vol. 20. No. 2. pp. 122-124.
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TY - JOUR
DO - 10.1016/j.mencom.2010.03.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.020
TI - A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids
T2 - Mendeleev Communications
AU - Vendilo, Andrey Grigorievich
AU - Djigailo, Dmitry Ivanovich
AU - Rönkkömäki, Hannu
AU - Lajunen, Marja
AU - Chernikova, Elena Aleksandrovna
AU - Lajunen, Lauri H.J.
AU - Pletnev, Igor Vladimirovich
AU - Popov, Konstantin Ivanovich
PY - 2010
DA - 2010/03/05
PB - Mendeleev Communications
SP - 122-124
IS - 2
VL - 20
ER -
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@article{2010_Vendilo,
author = {Andrey Grigorievich Vendilo and Dmitry Ivanovich Djigailo and Hannu Rönkkömäki and Marja Lajunen and Elena Aleksandrovna Chernikova and Lauri H.J. Lajunen and Igor Vladimirovich Pletnev and Konstantin Ivanovich Popov},
title = {A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.020},
number = {2},
pages = {122--124},
doi = {10.1016/j.mencom.2010.03.020}
}
MLA
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MLA Copy
Vendilo, Andrey Grigorievich, et al. “A correlation of caesium–18-crown-6 complex formation constants with the extraction capability for hydrophobic ionic liquids.” Mendeleev Communications, vol. 20, no. 2, Mar. 2010, pp. 122-124. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.020.

Abstract

Thermodynamic data for caesium complexation with 18-crown-6 in various hydrophobic room-temperature ionic liquids were measured using 133Cs NMR spectroscopy at 25°C; the stability constants correlate well with crown ether assisted extraction degree of caesium from water into room temperature ionic liquids indicating an importance of complex stability for the extraction process.

References

1.
Ionic liquids. Green solvents for the future
Earle M.J., Seddon K.R.
Pure and Applied Chemistry, 2000
2.
Separations of metal ions using ionic liquids: The challenges of multiple mechanisms
Cocalia V.A., Holbrey J.D., Gutowski K.E., Bridges N.J., Roqers R.D.
Tsinghua Science and Technology, 2006
3.
EXAFS Investigations of the Mechanism of Facilitated Ion Transfer into a Room-Temperature Ionic Liquid
Jensen M.P., Dzielawa J.A., Rickert P., Dietz M.L.
Journal of the American Chemical Society, 2002
4.
Traditional Extractants in Nontraditional Solvents:  Groups 1 and 2 Extraction by Crown Ethers in Room-Temperature Ionic Liquids
Visser A.E., Swatloski R.P., Reichert W.M., Griffin S.T., Rogers R.D.
Industrial & Engineering Chemistry Research, 2000
5.
Solvent extraction of strontium nitrate by a crown ether using room-temperature ionic liquids †
Dai S., Ju Y.H., Barnes C.E.
Journal of the Chemical Society Dalton Transactions, 1999
10.
Stability constants of cesium complexes with 18-crown-6 in ionic liquids
Vendilo A.G., Rönkkömäki H., Hannu-Kuure M., Lajunen M., Asikkala Y., Petrov A.A., Krasovsky V.G., Chernikova E.A., Oksman P., Lajunen L.H., Popov K.I.
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2008
13.
10.1016/j.mencom.2010.03.020_bib11
Abramov
Vestn. Mosk. Univ., Ser. 2: Khim., 2000