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Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones

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Pourali A. R. Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones // Mendeleev Communications. 2010. Vol. 20. No. 2. pp. 113-115.
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Pourali A. R. Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones // Mendeleev Communications. 2010. Vol. 20. No. 2. pp. 113-115.
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TY - JOUR
DO - 10.1016/j.mencom.2010.03.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.017
TI - Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones
T2 - Mendeleev Communications
AU - Pourali, Ali Reza
PY - 2010
DA - 2010/03/05
PB - Mendeleev Communications
SP - 113-115
IS - 2
VL - 20
ER -
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@article{2010_Pourali,
author = {Ali Reza Pourali},
title = {Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones},
journal = {Mendeleev Communications},
year = {2010},
volume = {20},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.017},
number = {2},
pages = {113--115},
doi = {10.1016/j.mencom.2010.03.017}
}
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Pourali, Ali Reza. “Polymer-supported Oxone and tert-butyl hydroperoxide: new reagents for the epoxidation of α,β-unsaturated aldehydes and ketones.” Mendeleev Communications, vol. 20, no. 2, Mar. 2010, pp. 113-115. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.03.017.

Keywords

epoxidation
hydroperoxides
polymer supported reagent
α,β-enones

Abstract

Efficient, mild and selective epoxidation of α,β-unsaturated aldehydes and ketones was performed using polyvinylpyrrolidonesupported Oxone (Oxone/PVP) and ButOOH/PVP.

References

1.
Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant
2.
Asymmetric Organocatalytic Epoxidation of α,β-Unsaturated Aldehydes with Hydrogen Peroxide
Marigo M., Franzén J., Poulsen T.B., Zhuang W., Jørgensen K.A.
Journal of the American Chemical Society, 2005
4.
Epoxidation of α,β-unsaturated ketones in water. An environmentally benign protocol
Fioroni G., Fringuelli F., Pizzo F., Vaccaro L.
Green Chemistry, 2003
5.
Chemical Transformation of Prostaglandin-A2:  A Novel Series of C-10 Halogenated, C-12 Hydroxylated Prostaglandin-A2 Analogues
6.
A. S. Rao, in Comprehensive Organic Synthesis, eds. B. M. Trost and I. Fleming, Pergamon Press, Oxford, 1991, vol. 7, p. 357.
8.
Über die Einwirkung von alkalischem Wasserstoffsuperoxyd auf ungesättigte Verbindungen
Weitz E., Scheffer A.
Berichte der deutschen chemischen Gesellschaft (A and B Series), 1921
9.
J. Breitenbach and A. Sanner, US Patent, 5674436, C07O, 1997.(Chem. Abstr., 1997, 126, 264400 v).
11.
10.1016/j.mencom.2010.03.017_bib8
Qiang
J. Chem. Res., 2005
13.
Microwave-Accelerated Epoxidation of α,β-Unsaturated Ketones with Urea- Hydrogen Peroxide
dos Santos A., Wendler E., Marques F.D., Simonelli F.
Letters in Organic Chemistry, 2004
14.
Dioxirane oxidations: Taming the reactivity-selectivity principle
Curci R., Dinoi A., Rubino M.F.
Pure and Applied Chemistry, 1995
16.
Dramatic Enhancement of Enone Epoxidation Rates in Nonionic Microemulsions
Wielpütz T., Sottmann T., Strey R., Schmidt F., Berkessel A.
Chemistry - A European Journal, 2006
17.
Asymmetric epoxidation of electron-deficient olefins
Porter M.J., Skidmore J.
Chemical Communications, 2000
19.
Multi-step organic synthesis using solid-supported reagents and scavengers: a new paradigm in chemical library generation
Ley S.V., Baxendale I.R., Bream R.N., Jackson P.S., Leach A.G., Longbottom D.A., Nesi M., Scott J.S., Storer R.I., Taylor S.J.
Journal of the Chemical Society Perkin Transactions 1, 2000
23.
Baeyer−Villiger Oxidation with Potassium Peroxomonosulfate Supported on Acidic Silica Gel
González-Núñez M.E., Mello R., Olmos A., Asensio G.
Journal of Organic Chemistry, 2005
24.
10.1016/j.mencom.2010.03.017_bib20
Panarin
Polym. Sci. A, 2000