Home / Publications / An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral

An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral

Vladimir Fedorovich Mironov 1, 2
Vladimir Fedorovich Mironov
, 
Yuliya Yu Borisova 2
Yuliya Yu Borisova
, 
Liliya Mullachmetovna Burnaeva 2
Liliya Mullachmetovna Burnaeva
, 
Dmitry Borisovich Krivolapov 1
Dmitry Borisovich Krivolapov
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Vladislav V Zverev 1
Vladislav V Zverev
, 
Rashid Zagitovich Musin 1
Rashid Zagitovich Musin
, 
Irina Vadimovna Konovalova 2
Irina Vadimovna Konovalova
10.1016/j.mencom.2010.01.017
Published 2009-12-30
Communication , Volume 20, Issue 1, 44-46
3
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Mironov V. F. et al. An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 44-46.
GOST all authors (up to 50) Copy
Mironov V. F., Borisova Y. Yu., Burnaeva L. M., Krivolapov D. B., Litvinov I. A., Zverev V. V., Musin R. Z., Konovalova I. V. An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 44-46.
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TY - JOUR
DO - 10.1016/j.mencom.2010.01.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.017
TI - An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral
T2 - Mendeleev Communications
AU - Mironov, Vladimir Fedorovich
AU - Borisova, Yuliya Yu
AU - Burnaeva, Liliya Mullachmetovna
AU - Krivolapov, Dmitry Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Zverev, Vladislav V
AU - Musin, Rashid Zagitovich
AU - Konovalova, Irina Vadimovna
PY - 2009
DA - 2009/12/30
PB - Mendeleev Communications
SP - 44-46
IS - 1
VL - 20
ER -
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@article{2009_Mironov,
author = {Vladimir Fedorovich Mironov and Yuliya Yu Borisova and Liliya Mullachmetovna Burnaeva and Dmitry Borisovich Krivolapov and Igor Anatol'evich Litvinov and Vladislav V Zverev and Rashid Zagitovich Musin and Irina Vadimovna Konovalova},
title = {An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral},
journal = {Mendeleev Communications},
year = {2009},
volume = {20},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.017},
number = {1},
pages = {44--46},
doi = {10.1016/j.mencom.2010.01.017}
}
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Mironov, Vladimir Fedorovich, et al. “An unusual cascade reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral.” Mendeleev Communications, vol. 20, no. 1, Dec. 2009, pp. 44-46. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.017.

Abstract

The reaction of 4,5-dihydro-4,4-bis(trifluoromethyl)-2-phenyl-6,7-(4-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-one with chloral (1:2) proceeds with evolving hexafluoroacetone and gives spiro{2-oxo-4-trichloromethyl-4,5-dihydro-2-phenyl-6,7-(4-chlorobenzo)[f]-1,3,2-dioxaphosphepine-5,2’-(3’-trichloromethyl)oxirane} with a high stereoselectivity. Configuration of the four chiral centres (P2SC4SC5SC3'S /P2RC4RC5RC3’R) was determined by a single crystal X-ray diffraction.

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