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Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer

Anton Eugen'evich Nikolaev 1
Anton Eugen'evich Nikolaev
, 
Vyacheslav Èngel'sovich Semenov 1
Vyacheslav Èngel'sovich Semenov
, 
Olga Aleksandrovna Lodochnikova 1
Olga Aleksandrovna Lodochnikova
, 
Shamil Kamil'evich Latypov 1
Shamil Kamil'evich Latypov
, 
Vladimir Savich Reznik 1
Vladimir Savich Reznik
10.1016/j.mencom.2010.01.002
Published 2009-12-30
Communication , Volume 20, Issue 1, 4-6
3
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Nikolaev A. E. et al. Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 4-6.
GOST all authors (up to 50) Copy
Nikolaev A. E., Semenov V. È., Lodochnikova O. A., Latypov S. K., Reznik V. S. Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 4-6.
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TY - JOUR
DO - 10.1016/j.mencom.2010.01.002
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.002
TI - Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer
T2 - Mendeleev Communications
AU - Nikolaev, Anton Eugen'evich
AU - Semenov, Vyacheslav Èngel'sovich
AU - Lodochnikova, Olga Aleksandrovna
AU - Latypov, Shamil Kamil'evich
AU - Reznik, Vladimir Savich
PY - 2009
DA - 2009/12/30
PB - Mendeleev Communications
SP - 4-6
IS - 1
VL - 20
ER -
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@article{2009_Nikolaev,
author = {Anton Eugen'evich Nikolaev and Vyacheslav Èngel'sovich Semenov and Olga Aleksandrovna Lodochnikova and Shamil Kamil'evich Latypov and Vladimir Savich Reznik},
title = {Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer},
journal = {Mendeleev Communications},
year = {2009},
volume = {20},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.002},
number = {1},
pages = {4--6},
doi = {10.1016/j.mencom.2010.01.002}
}
MLA
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Nikolaev, Anton Eugen'evich, et al. “Synthesis and structure of pyrimidinophanes with a sulfur atom in the spacer.” Mendeleev Communications, vol. 20, no. 1, Dec. 2009, pp. 4-6. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.002.

Keywords

Cyclization
macrocycle
pyrimidinophane
sulfonium salts
uracil

Abstract

The cyclization of 1,3-bis(ω-bromoalkyl)uracils with sodium sulfide led to pyrimidinophanes, containing one uracil unit and an S atom in the spacer, macrocyclic structure was confirmed by X-ray data; the S atom in bridge can be oxidized into sulfoxide or sulfone or converted into sulfonium ion.

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