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Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles

Alexei Dmitrievich Averin 1
Alexei Dmitrievich Averin
, 
Alexei Nikolaevich Uglov 1
Alexei Nikolaevich Uglov
, 
Alexey Konstantinovich Buryak 2
Alexey Konstantinovich Buryak
, 
Irina Petrovna Beletskaya 1, 2
Irina Petrovna Beletskaya
10.1016/j.mencom.2010.01.001
Published 2009-12-30
Communication , Volume 20, Issue 1, 1-3
7
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Averin A. D. et al. Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 1-3.
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Averin A. D., Uglov A. N., Buryak A. K., Beletskaya I. P. Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles // Mendeleev Communications. 2009. Vol. 20. No. 1. pp. 1-3.
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TY - JOUR
DO - 10.1016/j.mencom.2010.01.001
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.001
TI - Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles
T2 - Mendeleev Communications
AU - Averin, Alexei Dmitrievich
AU - Uglov, Alexei Nikolaevich
AU - Buryak, Alexey Konstantinovich
AU - Beletskaya, Irina Petrovna
PY - 2009
DA - 2009/12/30
PB - Mendeleev Communications
SP - 1-3
IS - 1
VL - 20
ER -
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@article{2009_Averin,
author = {Alexei Dmitrievich Averin and Alexei Nikolaevich Uglov and Alexey Konstantinovich Buryak and Irina Petrovna Beletskaya},
title = {Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles},
journal = {Mendeleev Communications},
year = {2009},
volume = {20},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.001},
number = {1},
pages = {1--3},
doi = {10.1016/j.mencom.2010.01.001}
}
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Averin, Alexei Dmitrievich, et al. “Pd-catalyzed amination of isomeric dibromobiphenyls: possibilities of one-step synthesis of macrocycles.” Mendeleev Communications, vol. 20, no. 1, Dec. 2009, pp. 1-3. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2010.01.001.

Abstract

The Pd-catalyzed amination of isomeric dibromobiphenyls using linear oxadiamines, tri-, tetra- and pentaamines was carried out. 4,4’-Dibromobiphenyl provided a macrocycle comprising one biphenyl and one oxadiamine unit in tiny yield only with the longest diamine; on contrary, 3,3’-dibromobiphenyl gave target macrocycles in good yields, while 2,2’-dibromobiphenyl afforded only acyclic products.

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