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One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action

Anatoly Nikolaevich Vereshchagin 1
Anatoly Nikolaevich Vereshchagin
,  , 
Nikita Olegovich Stepanov 1
Nikita Olegovich Stepanov
, 
Gennady Ivanovich Nikishin 1
Gennady Ivanovich Nikishin
10.1016/j.mencom.2009.11.010
Published 2009-11-02
Communication , Volume 19, Issue 6, 324-325
33
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Vereshchagin A. N. et al. One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action // Mendeleev Communications. 2009. Vol. 19. No. 6. pp. 324-325.
GOST all authors (up to 50) Copy
Vereshchagin A. N., Elinson M. N., Stepanov N. O., Nikishin G. I. One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action // Mendeleev Communications. 2009. Vol. 19. No. 6. pp. 324-325.
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TY - JOUR
DO - 10.1016/j.mencom.2009.11.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.010
TI - One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action
T2 - Mendeleev Communications
AU - Vereshchagin, Anatoly Nikolaevich
AU - Elinson, Michail Nikolaevich
AU - Stepanov, Nikita Olegovich
AU - Nikishin, Gennady Ivanovich
PY - 2009
DA - 2009/11/02
PB - Mendeleev Communications
SP - 324-325
IS - 6
VL - 19
ER -
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@article{2009_Vereshchagin,
author = {Anatoly Nikolaevich Vereshchagin and Michail Nikolaevich Elinson and Nikita Olegovich Stepanov and Gennady Ivanovich Nikishin},
title = {One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.010},
number = {6},
pages = {324--325},
doi = {10.1016/j.mencom.2009.11.010}
}
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Vereshchagin, Anatoly Nikolaevich, et al. “One-pot cascade assembling of 3-substituted tetracyanocyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action.” Mendeleev Communications, vol. 19, no. 6, Nov. 2009, pp. 324-325. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.010.

Abstract

The new cascade reaction was found: the formation of cyclopropanes from alkylidenemalononitriles and malononitrile by the only bromine direct action; the action of aqueous bromine on the equal amounts of alkylidenemalononitriles and malononitrile in EtOH–H2O solutions results in the formation of 3-substituted 1,1,2,2-tetracyanocyclopropanes in 55–98% yields.

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