Home / Publications / Reliable rate constant determination for heterogeneous electron transfer: CrEDTA

Reliable rate constant determination for heterogeneous electron transfer: CrEDTA

Alexander Semenovich Kotkin 1
Alexander Semenovich Kotkin
Alexander Georgievich Krivenko 1
Alexander Georgievich Krivenko
Galina Nesterovna Botukhova 2
Galina Nesterovna Botukhova
Galina Aleksandrovna Tsirlina 2
Galina Aleksandrovna Tsirlina
Published 2009-11-02
CommunicationVolume 19, Issue 6, 314-316
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Kotkin A. S. et al. Reliable rate constant determination for heterogeneous electron transfer: CrEDTA– // Mendeleev Communications. 2009. Vol. 19. No. 6. pp. 314-316.
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Kotkin A. S., Krivenko A. G., Botukhova G. N., Tsirlina G. A. Reliable rate constant determination for heterogeneous electron transfer: CrEDTA– // Mendeleev Communications. 2009. Vol. 19. No. 6. pp. 314-316.
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TY - JOUR
DO - 10.1016/j.mencom.2009.11.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.006
TI - Reliable rate constant determination for heterogeneous electron transfer: CrEDTA–
T2 - Mendeleev Communications
AU - Kotkin, Alexander Semenovich
AU - Krivenko, Alexander Georgievich
AU - Botukhova, Galina Nesterovna
AU - Tsirlina, Galina Aleksandrovna
PY - 2009
DA - 2009/11/02
PB - Mendeleev Communications
SP - 314-316
IS - 6
VL - 19
ER -
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@article{2009_Kotkin,
author = {Alexander Semenovich Kotkin and Alexander Georgievich Krivenko and Galina Nesterovna Botukhova and Galina Aleksandrovna Tsirlina},
title = {Reliable rate constant determination for heterogeneous electron transfer: CrEDTA–},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.006},
number = {6},
pages = {314--316},
doi = {10.1016/j.mencom.2009.11.006}
}
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Kotkin, Alexander Semenovich, et al. “Reliable rate constant determination for heterogeneous electron transfer: CrEDTA–.” Mendeleev Communications, vol. 19, no. 6, Nov. 2009, pp. 314-316. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.11.006.

Abstract

Pulse and steady-state photoemission techniques are applied to determine the heterogeneous rate constant of CrEDTA– reduction on liquid mercury. The resulting value (too high for polarographic determination and available earlier only for amalgamated gold) is important for experimental verification of various predictions of the electron transfer theory.

References

1.
Activation Energy of Electron Transfer between a Metal Electrode and Reagents of Nonspherical Form and Complicated Charge Distribution. Cr(EDTA) Complexes
3.
Misleading aspects of the viscosity effect on the heterogeneous electron transfer reactions
Nazmutdinov R.R., Tsirlina G.A., Manyurov I.R., Bronshtein M.D., Titova N.V., Kuzminova Z.V.
Chemical Physics, 2006
4.
10.1016/j.mencom.2009.11.006_bib4
Khrushcheva
Elektrokhimiya, 1998
5.
10.1016/j.mencom.2009.11.006_bib5
Krivenko
Elektrokhimiya, 2005
6.
10.1016/j.mencom.2009.11.006_bib6
Krivenko
Elektrokhimiya, 2005
7.
Mechanism of electroreduction of intermediates with and without a proton donor
8.
The electrochemistry of short-lived intermediate species
Benderskii V.A., Krivenko A.G.
Russian Chemical Reviews, 1990
9.
10.1016/j.mencom.2009.11.006_bib9
Khrushcheva
Elektrokhimiya, 1996
10.
V. A. Benderskii, A. V. Benderskii, Laser Electrochemistry of Intermediates, CRC Press, New York, 1995.
11.
10.1016/j.mencom.2009.11.006_bib11
Benderskii
J. Electroanal. Chem., 1977
12.
Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution
Buxton G.V., Greenstock C.L., Helman W.P., Ross A.B.
Journal of Physical and Chemical Reference Data, 1988
14.
Life of the Tafel equation: Current understanding and prospects for the second century
Petrii O.A., Nazmutdinov R.R., Bronshtein M.D., Tsirlina G.A.
Electrochimica Acta, 2007
15.
Asymmetry of inner-sphere reorganization energy for heterogeneous electron transfer
Tsirlina G.A., Kharkats Y.I., Nazmutdinov R.R., Petrii O.A.
Journal of Electroanalytical Chemistry, 1998