Home / Publications / A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules

A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules

Kirill Borisovich Nuzhdin 1
Kirill Borisovich Nuzhdin
, 
Aleksey Viktorovich Kobzarenko 1
Aleksey Viktorovich Kobzarenko
, 
Igor Ivanovich Barabanov 2
Igor Ivanovich Barabanov
, 
Vladimir Isaevich Feldman 1, 3
Vladimir Isaevich Feldman
10.1016/j.mencom.2009.09.012
Published 2009-09-15
Communication , Volume 19, Issue 5, 268-269
5
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Nuzhdin K. B. et al. A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules // Mendeleev Communications. 2009. Vol. 19. No. 5. pp. 268-269.
GOST all authors (up to 50) Copy
Nuzhdin K. B., Kobzarenko A. V., Barabanov I. I., Feldman V. I. A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules // Mendeleev Communications. 2009. Vol. 19. No. 5. pp. 268-269.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2009.09.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.012
TI - A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules
T2 - Mendeleev Communications
AU - Nuzhdin, Kirill Borisovich
AU - Kobzarenko, Aleksey Viktorovich
AU - Barabanov, Igor Ivanovich
AU - Feldman, Vladimir Isaevich
PY - 2009
DA - 2009/09/15
PB - Mendeleev Communications
SP - 268-269
IS - 5
VL - 19
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{2009_Nuzhdin,
author = {Kirill Borisovich Nuzhdin and Aleksey Viktorovich Kobzarenko and Igor Ivanovich Barabanov and Vladimir Isaevich Feldman},
title = {A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.012},
number = {5},
pages = {268--269},
doi = {10.1016/j.mencom.2009.09.012}
}
MLA
Cite this
MLA Copy
Nuzhdin, Kirill Borisovich, et al. “A ‘magic bridge’: effect of methylene chain length on the photochemistry of radical cations produced from bifunctional X–(CH2)n–Y molecules.” Mendeleev Communications, vol. 19, no. 5, Sep. 2009, pp. 268-269. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.012.

Keywords

bifunctional compounds
EPR
radical cations

Abstract

The radical cations of aminoamides Me2N(CH2)nC(O)NMe2 and aminoethers Me2N(CH2)nOMe reveal selective photoinduced intramolecular H transfer from methylene bridge at a specific chain length (n = 3).

References

1.
Electronic absorption spectra of aliphatic diamine radical cations. Conformation-dependent charge delocalization
G??bicki J., Marcinek A., Stradowski C.
Journal of Physical Organic Chemistry, 1990
2.
Diketone radical cations: Ketonic and enolic forms as revealed by matrix EPR studies and DFT calculations
Nuzhdin K.B., Feldman V.I., Kobzarenko A.V.
Journal of Physical Chemistry A, 2007
4.
Nuzhdin K.B., Feldman V.I., Kobzarenko A.V.
Mendeleev Communications, 2008
6.
D. N. Laikov, Ph. D. Thesis (Phys. Math.), M. V. Lomonosov Moscow State University, Moscow, 2000.(in Russian).
8.
10.1016/j.mencom.2009.09.012_bib8
Williams
Radiat. Phys. Chem., 1988
9.
Reactions of radical cations of acetals: Evidence for unimolecular decomposition
Baranova I.A., Feldman V.I., Belevskii V.N.
Journal of Radioanalytical and Nuclear Chemistry, 1988