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Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media

Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Andrei Semenovich Mendkovich 1
Andrei Semenovich Mendkovich
, 
Ludmila Vasil'evna Mikhalchenko 1
Ludmila Vasil'evna Mikhalchenko
, 
Alexander Il'ich Rusakov 1
Alexander Il'ich Rusakov
, 
Vadim Pavlovich Gul'tyai 1
Vadim Pavlovich Gul'tyai
10.1016/j.mencom.2009.09.008
Published 2009-09-15
Communication , Volume 19, Issue 5, 258-259
7
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Syroeshkin M. A. et al. Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media // Mendeleev Communications. 2009. Vol. 19. No. 5. pp. 258-259.
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Syroeshkin M. A., Mendkovich A. S., Mikhalchenko L. V., Rusakov A. I., Gul'tyai V. P. Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media // Mendeleev Communications. 2009. Vol. 19. No. 5. pp. 258-259.
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TY - JOUR
DO - 10.1016/j.mencom.2009.09.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.008
TI - Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media
T2 - Mendeleev Communications
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Mendkovich, Andrei Semenovich
AU - Mikhalchenko, Ludmila Vasil'evna
AU - Rusakov, Alexander Il'ich
AU - Gul'tyai, Vadim Pavlovich
PY - 2009
DA - 2009/09/15
PB - Mendeleev Communications
SP - 258-259
IS - 5
VL - 19
ER -
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@article{2009_Syroeshkin,
author = {Mikhail Aleksandrovich Syroeshkin and Andrei Semenovich Mendkovich and Ludmila Vasil'evna Mikhalchenko and Alexander Il'ich Rusakov and Vadim Pavlovich Gul'tyai},
title = {Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.008},
number = {5},
pages = {258--259},
doi = {10.1016/j.mencom.2009.09.008}
}
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Syroeshkin, Mikhail Aleksandrovich, et al. “Self-protonation upon the electroreduction of 2- and 4-nitrophenylhydroxylamines in aprotic media.” Mendeleev Communications, vol. 19, no. 5, Sep. 2009, pp. 258-259. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.09.008.

Abstract

Cyclic voltammetry and controlled potential electrolysis were used to show that radical anions of 2- and 4-nitrophenylhydroxylamines electrochemically generated in a 0.1M Bu4NClO4 solution in DMF undergo protonation with the starting compounds (self-protonation) followed by the formation of the corresponding nitroanilines.

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