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Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6

Andrey Grigorievich Vendilo 1
Andrey Grigorievich Vendilo
, 
Hannu Rönkkömäki 2
Hannu Rönkkömäki
, 
Milija Hannu-Kuure 3
Milija Hannu-Kuure
, 
Marja Lajunen 3
Marja Lajunen
, 
Janne Asikkala 3
Janne Asikkala
, 
Elena Aleksandrovna Chernikova 4
Elena Aleksandrovna Chernikova
, 
Lauri H.J. Lajunen 3
Lauri H.J. Lajunen
, 
Tapani Tuomi 5
Tapani Tuomi
, 
Konstantin Ivanovich Popov 6
Konstantin Ivanovich Popov
10.1016/j.mencom.2009.07.007
Published 2009-07-03
Communication , Volume 19, Issue 4, 196-197
4
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Vendilo A. G. et al. Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6 // Mendeleev Communications. 2009. Vol. 19. No. 4. pp. 196-197.
GOST all authors (up to 50) Copy
Vendilo A. G., Rönkkömäki H., Hannu-Kuure M., Lajunen M., Asikkala J., Chernikova E. A., Lajunen L. H., Tuomi T., Popov K. I. Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6 // Mendeleev Communications. 2009. Vol. 19. No. 4. pp. 196-197.
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TY - JOUR
DO - 10.1016/j.mencom.2009.07.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.007
TI - Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6
T2 - Mendeleev Communications
AU - Vendilo, Andrey Grigorievich
AU - Rönkkömäki, Hannu
AU - Hannu-Kuure, Milija
AU - Lajunen, Marja
AU - Asikkala, Janne
AU - Chernikova, Elena Aleksandrovna
AU - Lajunen, Lauri H.J.
AU - Tuomi, Tapani
AU - Popov, Konstantin Ivanovich
PY - 2009
DA - 2009/07/03
PB - Mendeleev Communications
SP - 196-197
IS - 4
VL - 19
ER -
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@article{2009_Vendilo,
author = {Andrey Grigorievich Vendilo and Hannu Rönkkömäki and Milija Hannu-Kuure and Marja Lajunen and Janne Asikkala and Elena Aleksandrovna Chernikova and Lauri H.J. Lajunen and Tapani Tuomi and Konstantin Ivanovich Popov},
title = {Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.007},
number = {4},
pages = {196--197},
doi = {10.1016/j.mencom.2009.07.007}
}
MLA
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MLA Copy
Vendilo, Andrey Grigorievich, et al. “Thermodynamics of complex formation in ionic liquids: cesium complexes with 18-crown-6.” Mendeleev Communications, vol. 19, no. 4, Jul. 2009, pp. 196-197. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.007.

Abstract

Thermodynamic data for the formation of cesium complexes with 18-crown-6 (18C6, L) [Cs(18C6)]+ in N-butyl-4-methyl- pyridinium tetrafluoroborate, 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium dicyanamide, measured using 133Cs NMR spectroscopy at 23–50 ̊C, revealed that the stability of cesium complex in ionic liquids is affected by the nature of both cation and anion of room temperature ionic liquid and is in the range between the values found for water and DMF.

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