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New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane

Rustam Muratovich Kagirov 1
Rustam Muratovich Kagirov
Ildar Khamidovich Rizvanov 1
Ildar Khamidovich Rizvanov
Vladimir Ivanovich Morozov 1
Vladimir Ivanovich Morozov
Published 2009-07-03
CommunicationVolume 19, Issue 4, 190-192
4
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Yakhvarov D. G. et al. New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane // Mendeleev Communications. 2009. Vol. 19. No. 4. pp. 190-192.
GOST all authors (up to 50) Copy
Yakhvarov D. G., Kagirov R. M., Rizvanov I. K., Morozov V. I., Sinyashin O. G. New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane // Mendeleev Communications. 2009. Vol. 19. No. 4. pp. 190-192.
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TY - JOUR
DO - 10.1016/j.mencom.2009.07.005
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.005
TI - New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane
T2 - Mendeleev Communications
AU - Yakhvarov, Dmitry Grigorievich
AU - Kagirov, Rustam Muratovich
AU - Rizvanov, Ildar Khamidovich
AU - Morozov, Vladimir Ivanovich
AU - Sinyashin, Oleg Gerol'dovich
PY - 2009
DA - 2009/07/03
PB - Mendeleev Communications
SP - 190-192
IS - 4
VL - 19
ER -
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@article{2009_Yakhvarov,
author = {Dmitry Grigorievich Yakhvarov and Rustam Muratovich Kagirov and Ildar Khamidovich Rizvanov and Vladimir Ivanovich Morozov and Oleg Gerol'dovich Sinyashin},
title = {New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.005},
number = {4},
pages = {190--192},
doi = {10.1016/j.mencom.2009.07.005}
}
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Yakhvarov, Dmitry Grigorievich, et al. “New aspects of the electroreduction of palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane.” Mendeleev Communications, vol. 19, no. 4, Jul. 2009, pp. 190-192. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.07.005.

Abstract

The electrochemical reduction of a mono-chelate palladium dichloride complex with 1,2-bis(diphenylphosphino)ethane (dppe) in DMF results in formation of highly reactive mono-chelate palladium(0) complex, which reacts with initial complex by reaction of the ligand abstraction forming stable bischelate complex [Pd0(dppe)2] and palladium dichloride.

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