Home / Publications / Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4]

Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4]

Lyudmila Alexandrovna Kushch 1
Lyudmila Alexandrovna Kushch
, 
Gennady Viktorovich Shilov 1
Gennady Viktorovich Shilov
,  , 
Eduard Borisovich Yagubskii 1
Eduard Borisovich Yagubskii
10.1016/j.mencom.2009.05.021
Published 2009-05-08
Communication , Volume 19, Issue 3, 170-171
6
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Kushch L. A. et al. Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4] // Mendeleev Communications. 2009. Vol. 19. No. 3. pp. 170-171.
GOST all authors (up to 50) Copy
Kushch L. A., Shilov G. V., Morgunov R. B., Yagubskii E. B. Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4] // Mendeleev Communications. 2009. Vol. 19. No. 3. pp. 170-171.
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TY - JOUR
DO - 10.1016/j.mencom.2009.05.021
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.021
TI - Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4]
T2 - Mendeleev Communications
AU - Kushch, Lyudmila Alexandrovna
AU - Shilov, Gennady Viktorovich
AU - Morgunov, Roman Borisovich
AU - Yagubskii, Eduard Borisovich
PY - 2009
DA - 2009/05/08
PB - Mendeleev Communications
SP - 170-171
IS - 3
VL - 19
ER -
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@article{2009_Kushch,
author = {Lyudmila Alexandrovna Kushch and Gennady Viktorovich Shilov and Roman Borisovich Morgunov and Eduard Borisovich Yagubskii},
title = {Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4]},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.021},
number = {3},
pages = {170--171},
doi = {10.1016/j.mencom.2009.05.021}
}
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Kushch, Lyudmila Alexandrovna, et al. “Reduction fragmentation of the [Mn12O12(O2CCHCl2)16(H2O)4] oxocarboxylate cluster to [Mn6O2(O2CCHCl2)10(MeCN)4].” Mendeleev Communications, vol. 19, no. 3, May. 2009, pp. 170-171. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.021.

Keywords

hexanuclear cluster
oxocarboxylate Mn12 cluster
single molecule magnets
tetrathiotetracene

Abstract

The reaction of the [Mn12O12(O2CCHCl2)16(H2O)4] cluster with tetrathiotetracene triiodide has been studied and, for the first time, reduction fragmentation of Mn12 cluster to Mn6 cluster has been found.

References

1.
Quantum Tunneling of Magnetization and Related Phenomena in Molecular Materials
Gatteschi D., Sessoli R.
Angewandte Chemie - International Edition, 2003
5.
Preparation, crystal structure, magnetic properties, and chemical reactions of a hexanuclear mixed valence manganese carboxylate
Baikie A.R., Howes A.J., Hursthouse M.B., Quick A.B., Thornton P.
Journal of the Chemical Society Chemical Communications, 1986
7.
10.1016/j.mencom.2009.05.021_bib7
Batsanov
Koord. Khim., 1994
8.
10.1016/j.mencom.2009.05.021_bib8
Halcrow
Acta Crystallogr., 1995
10.
Synthesis, Structure, and Magnetism of Heterometallic Carboxylate Complexes [MnIII2MII4O2(PhCOO)10(DMF)4], M = MnII, CoII, NiII
Gavrilenko K.S., Punin S.V., Cador O., Golhen S., Ouahab L., Pavlishchuk V.V.
Inorganic Chemistry, 2005
12.
10.1016/j.mencom.2009.05.021_bib12
Kaminskii
J. Phys. C3, 1983
13.
E. B. Yagubskii, L. A. Kushch and R. B. Morgunov, Abstracts of IV International Conference ‘High-spin Molecules and Molecular Magnets’, Ekaterinburg, October 14-19, 2008, p. 60.