Keywords
formamidines
imido-deoxygenation
metathesis
molybdenum
N-sulfinylamines
sulfurdiimines
Abstract
Dimethylformamide undergoes molybdenum-mediated metathetical imido-deoxygenation with ortho-substituted by donor atoms N-sulfinylanilines affording formamidines; N-sulfinylamines undergo molybdenum-mediated condensation into sulfurdiimines.
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