Home / Publications / Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution

Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution

Evgeny Borisovich Tsupak 1
Evgeny Borisovich Tsupak
Ivan A Gavrilenko 1
Ivan A Gavrilenko
Vladimir Vladimirovich Kostrub 1
Vladimir Vladimirovich Kostrub
Published 2009-05-08
CommunicationVolume 19, Issue 3, 157-158
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Tsupak E. B., Gavrilenko I. A., Kostrub V. V. Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution // Mendeleev Communications. 2009. Vol. 19. No. 3. pp. 157-158.
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Tsupak E. B., Gavrilenko I. A., Kostrub V. V. Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution // Mendeleev Communications. 2009. Vol. 19. No. 3. pp. 157-158.
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TY - JOUR
DO - 10.1016/j.mencom.2009.05.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.015
TI - Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution
T2 - Mendeleev Communications
AU - Tsupak, Evgeny Borisovich
AU - Gavrilenko, Ivan A
AU - Kostrub, Vladimir Vladimirovich
PY - 2009
DA - 2009/05/08
PB - Mendeleev Communications
SP - 157-158
IS - 3
VL - 19
ER -
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@article{2009_Tsupak,
author = {Evgeny Borisovich Tsupak and Ivan A Gavrilenko and Vladimir Vladimirovich Kostrub},
title = {Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.015},
number = {3},
pages = {157--158},
doi = {10.1016/j.mencom.2009.05.015}
}
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Tsupak, Evgeny Borisovich, et al. “Generation and properties of the 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation in a chloroform–trifluoroacetic acid solution.” Mendeleev Communications, vol. 19, no. 3, May. 2009, pp. 157-158. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.05.015.

Abstract

The 1,3-dimethyl-2,4-dioxo-1H,2H,3H,4H-pyrano[4,3-d]pyrimidinium cation has been prepared by means of acid-catalyzed cyclization of 1,3-dimethyl-6-(2-dimethylaminoethenyl)pyrimidine-2,4(1H,3H)-dione in a chloroform–trifluoroacetic acid solution, and its reactivity towards N-nucleophiles has been determined.

References

1.
A. T. Balaban, A. Dinculescu, G. N. Dorofeenko, G. W. Fischer, A. V. Koblik, V. V. Mezheritskii and W. Schroth, in Adv. Heterocycl. Chem., Suppl. 2, Academic Press, New York, 1982.
2.
Benzo[c] Pyrlium Salts: Syntheses, Reactions, and Physical Properties
Kuznetsov E.V., Shcherbakova I.V., Balaban A.T.
Advances in Heterocyclic Chemistry, 1990
3.
10.1016/j.mencom.2009.05.015_bib3
Tolkunov
Khim. Geterotsikl. Soedin., 2005
4.
10.1016/j.mencom.2009.05.015_bib4
Tolkunov
Khim. Geterotsikl. Soedin., 2005
5.
10.1016/j.mencom.2009.05.015_bib5
Kryuchkov
Khim. Geterotsikl. Soedin., 2005
6.
10.1016/j.mencom.2009.05.015_bib6
Tsupak
Izv. Akad. Nauk, Ser. Khim., 2007
8.
Synthesis of azaphilones and related molecules by employing cycloisomerization of o-alkynylbenzaldehydes.
9.
CONVENIENT SYNTHESIS OF PYRIDO4,3-DPYRIMIDINE-2,4-(1H, 3H)-DIONES
Hirota K., Nakazawa Y., Kitade Y., Sajiki H.
Heterocycles, 1998
10.
10.1016/j.mencom.2009.05.015_bib10
Dorofeenko
Khim. Geterotsikl. Soedin., 1974
11.
A. Albert and E. P. Serjeant, Ionization Constants of Acids and Bases: a Laboratory Manual, Methuen, London, 1962.