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Ozonolysis of verbenone in aprotic solvents

Olga Sergeevna Kukovinets 1
Olga Sergeevna Kukovinets
, 
Tatyana Ivanovna Zvereva 1
Tatyana Ivanovna Zvereva
, 
Natalia Nurullovna Kabal'nova 2
Natalia Nurullovna Kabal'nova
, 
Vakhtang Gayozovich Kasradze 2
Vakhtang Gayozovich Kasradze
, 
Elena Viktorovna Salimova 2
Elena Viktorovna Salimova
, 
Lyucia Rimovna Khalitova 2
Lyucia Rimovna Khalitova
, 
Marat Ibragimovich Abdullin 1
Marat Ibragimovich Abdullin
, 
Leonid Vasilevich Spirikhin 2
Leonid Vasilevich Spirikhin
10.1016/j.mencom.2009.03.019
Published 2009-03-10
Communication , Volume 19, Issue 2, 106-107
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Kukovinets O. S. et al. Ozonolysis of verbenone in aprotic solvents // Mendeleev Communications. 2009. Vol. 19. No. 2. pp. 106-107.
GOST all authors (up to 50) Copy
Kukovinets O. S., Zvereva T. I., Kabal'nova N. N., Kasradze V. G., Salimova E. V., Khalitova L. R., Abdullin M. I., Spirikhin L. V. Ozonolysis of verbenone in aprotic solvents // Mendeleev Communications. 2009. Vol. 19. No. 2. pp. 106-107.
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TY - JOUR
DO - 10.1016/j.mencom.2009.03.019
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.019
TI - Ozonolysis of verbenone in aprotic solvents
T2 - Mendeleev Communications
AU - Kukovinets, Olga Sergeevna
AU - Zvereva, Tatyana Ivanovna
AU - Kabal'nova, Natalia Nurullovna
AU - Kasradze, Vakhtang Gayozovich
AU - Salimova, Elena Viktorovna
AU - Khalitova, Lyucia Rimovna
AU - Abdullin, Marat Ibragimovich
AU - Spirikhin, Leonid Vasilevich
PY - 2009
DA - 2009/03/10
PB - Mendeleev Communications
SP - 106-107
IS - 2
VL - 19
ER -
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@article{2009_Kukovinets,
author = {Olga Sergeevna Kukovinets and Tatyana Ivanovna Zvereva and Natalia Nurullovna Kabal'nova and Vakhtang Gayozovich Kasradze and Elena Viktorovna Salimova and Lyucia Rimovna Khalitova and Marat Ibragimovich Abdullin and Leonid Vasilevich Spirikhin},
title = {Ozonolysis of verbenone in aprotic solvents},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.019},
number = {2},
pages = {106--107},
doi = {10.1016/j.mencom.2009.03.019}
}
MLA
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MLA Copy
Kukovinets, Olga Sergeevna, et al. “Ozonolysis of verbenone in aprotic solvents.” Mendeleev Communications, vol. 19, no. 2, Mar. 2009, pp. 106-107. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.019.

Keywords

(1R
3S)-3-acetyl-2,2-dimethylcyclobutane carboxylic acid
aprotonic solvents
mechanism of ozonolysis
ozonolysis of verbenone

Abstract

The ozonolysis of verbenone in methylene chloride and acetonitrile at –60 and 0°C proceeds with cleavage of the double bond and neighbouring σ-bond to give (1R,3S)-acetyl-2,2-dimethylcyclobutane carboxylic acid. The mechanism of the reaction has been proposed.

References

1.
10.1016/j.mencom.2009.03.019_bib1
Kukovinets
Khim. Prir. Soedin., 2006
2.
10.1016/j.mencom.2009.03.019_bib2
Galin
Zh. Org. Khim., 2001
3.
10.1016/j.mencom.2009.03.019_bib3
Kharisov
Zh. Org. Khim., 2002
4.
10.1016/j.mencom.2009.03.019_bib4
Shereshovets
Neftekhimiya, 1980
5.
O. A. Reutov, A. L. Kurts and K. P. Butin, Organicheskaya Khimiya, BINOM, Moscow, 2004, vol. 3. (in Russian).
6.
10.1016/j.mencom.2009.03.019_bib6
Komissarova
Izv. Akad. Nauk SSSR, Ser. Khim., 1978