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Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations

Ludmila Vasil'evna Mikhalchenko 1
Ludmila Vasil'evna Mikhalchenko
, 
Andrei Semenovich Mendkovich 1
Andrei Semenovich Mendkovich
, 
Mikhail Aleksandrovich Syroeshkin 1
Mikhail Aleksandrovich Syroeshkin
, 
Vadim Pavlovich Gul'tyai 1
Vadim Pavlovich Gul'tyai
10.1016/j.mencom.2009.03.015
Published 2009-03-10
Communication , Volume 19, Issue 2, 96-98
5
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Mikhalchenko L. V. et al. Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations // Mendeleev Communications. 2009. Vol. 19. No. 2. pp. 96-98.
GOST all authors (up to 50) Copy
Mikhalchenko L. V., Mendkovich A. S., Syroeshkin M. A., Gul'tyai V. P. Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations // Mendeleev Communications. 2009. Vol. 19. No. 2. pp. 96-98.
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TY - JOUR
DO - 10.1016/j.mencom.2009.03.015
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.015
TI - Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations
T2 - Mendeleev Communications
AU - Mikhalchenko, Ludmila Vasil'evna
AU - Mendkovich, Andrei Semenovich
AU - Syroeshkin, Mikhail Aleksandrovich
AU - Gul'tyai, Vadim Pavlovich
PY - 2009
DA - 2009/03/10
PB - Mendeleev Communications
SP - 96-98
IS - 2
VL - 19
ER -
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@article{2009_Mikhalchenko,
author = {Ludmila Vasil'evna Mikhalchenko and Andrei Semenovich Mendkovich and Mikhail Aleksandrovich Syroeshkin and Vadim Pavlovich Gul'tyai},
title = {Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations},
journal = {Mendeleev Communications},
year = {2009},
volume = {19},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.015},
number = {2},
pages = {96--98},
doi = {10.1016/j.mencom.2009.03.015}
}
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Mikhalchenko, Ludmila Vasil'evna, et al. “Kinetics of the 1,3-dinitrobenzene dianion protonation with 1-butyl-3-methylimidazolium cations.” Mendeleev Communications, vol. 19, no. 2, Mar. 2009, pp. 96-98. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2009.03.015.

Keywords

1-butyl-3-methylimidazolium tetrafluoroborate
1,3-dinitrobenzene
chronoamperometry
cyclic voltammetry
electroreduction

Abstract

To estimate the applicability of 1-butyl-3-methylimidazolium (bmim+) cation as an electrolyte for electrochemistry, the rate constant of the 1,3-dinitrobenzene dianion protonation with bmim+ in DMF has been measured by cyclic voltammetry and chronoamperometry as 100±30 and 82±6 dm3 mol–1 s–1 and compared with the values for phenol.

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