Abstract
4,4-Bis(trifluoromethyl)-4,5-dihydro-2-phenylbenzo[e]- and 4,4-bis(trifluoromethyl)-4,5-dihydro-2-phenyl-(4’-chlorobenzo)[e]-1,3,2-dioxaphosphepin-5-ones react with hexafluoroacetone to form unusual propeller type structures – 3,3,10,10-tetrakis-(trifluoromethyl)-1-phenyl-6,7-benzo- and 3,3,10,10-tetrakis(trifluoromethyl)-1-phenyl-6,7-(4’-chlorobenzo)-2,4,8,9-tetraoxa-1-phosphatricyclo[3.3.2.01,5]decenes (5-carbaphosphatrane derivatives), the structure of which has been determined by NMR spectroscopy and single crystal X-ray diffraction analysis.
References
1.
Pudovik A.N., Konovalova I.V., Burnaeva L.A.
Synthesis,
1986
2.
Mironov V.F., Konovalova I.V., Burnaeva L.M., Ofitserov E.N.
Russian Chemical Reviews,
1996
3.
Neda I., Kaukorat T., Schmutzler R., Niemeyer U., Kutscher B., Pohl J.
Phosphorus, Sulfur and Silicon and the Related Elements,
2000
4.
10.1016/j.mencom.2009.01.014_bib4
Mironov
Zh. Org. Khim.,
1996
5.
Kobayashi J., Goto K., Kawashima T.
Journal of the American Chemical Society,
2001
6.
Kobayashi J., Goto K., Kawashima T., Schmidt M.W., Nagase S.
Journal of the American Chemical Society,
2002
7.
Nakafuji S., Kobayashi J., Kawashima T., Schmidt M.W.
Inorganic Chemistry,
2005
8.
Kobayashi J., Goto K., Kawashima T., Schmidt M.W., Nagase S.
Chemistry - A European Journal,
2006
9.
Kumara Swamy K.C., Satish Kumar N.
Accounts of Chemical Research,
2006
10.
Marcos E., Crehuet R., Anglada J.M.
Journal of Chemical Theory and Computation,
2007
11.
Range K., McGrath M.J., Lopez X., York D.M.
Journal of the American Chemical Society,
2004
12.
Kajiyama K., Yoshimune M., Nakamoto M., Matsukawa S., Kojima S., Akiba K.
Organic Letters,
2001
13.
Matsukawa S., Kojima S., Kajiyama K., Yamamoto Y., Akiba K., Re S., Nagase S.
Journal of the American Chemical Society,
2002
14.
Kojima S., Kajiyama K., Nakamoto M., Akiba K.
Journal of the American Chemical Society,
1996
15.
Kojima S., Sugino M., Matsukawa S., Nakamoto M., Akiba K.
Journal of the American Chemical Society,
2002
16.
Kajiyama K., Yoshimune M., Kojima S., Akiba K.
European Journal of Organic Chemistry,
2006
17.
Adachi T., Matsukawa S., Nakamoto M., Kajiyama K., Kojima S., Yamamoto Y., Akiba K., Re S., Nagase S.
Inorganic Chemistry,
2006
18.
Nakamoto M., Kojima S., Matsukawa S., Yamamoto Y., Akiba K.
Journal of Organometallic Chemistry,
2002
19.
L. H. Straver and A. J. Schierbeek, MolEN. Structure Determination System. Vol. 1. Program Description, Nonius B.V., Delft, 1994.
20.
Altomare A., Cascarano G., Giacovazzo C., Viterbo D.
Acta Crystallographica Section A Foundations of Crystallography,
1991
21.
G. M. Sheldrick,SHELX-97. Programs for Crystal Structure Analysis (Release 97-2), University of Göttingen, Germany, 1997.
22.
Farrugia L.J.
Journal of Applied Crystallography,
1999
23.
10.1016/j.mencom.2009.01.014_bib23
Spek
Acta Crystallogr., Sect. A,
1990