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Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction

Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
, 
Sergey Franzevich Vasilevskii 2
Sergey Franzevich Vasilevskii
, 
Nina Kuzminichna Gusarova 1
Nina Kuzminichna Gusarova
, 
Svetlana Filippovna Malysheva 1
Svetlana Filippovna Malysheva
, 
Denis Sergeevich Baranov 2
Denis Sergeevich Baranov
, 
Victor Il'ich Mamatyuk 3
Victor Il'ich Mamatyuk
, 
Yuriy Vasil'evich Gatilov 3
Yuriy Vasil'evich Gatilov
10.1016/j.mencom.2008.11.010
Published 2008-11-01
Communication , Volume 18, Issue 6, 318-319
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Trofimov B. A. et al. Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 318-319.
GOST all authors (up to 50) Copy
Trofimov B. A., Vasilevskii S. F., Gusarova N. K., Malysheva S. F., Baranov D. S., Mamatyuk V. I., Gatilov Y. V. Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 318-319.
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TY - JOUR
DO - 10.1016/j.mencom.2008.11.010
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.010
TI - Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction
T2 - Mendeleev Communications
AU - Trofimov, Boris Aleksandrovich
AU - Vasilevskii, Sergey Franzevich
AU - Gusarova, Nina Kuzminichna
AU - Malysheva, Svetlana Filippovna
AU - Baranov, Denis Sergeevich
AU - Mamatyuk, Victor Il'ich
AU - Gatilov, Yuriy Vasil'evich
PY - 2008
DA - 2008/11/01
PB - Mendeleev Communications
SP - 318-319
IS - 6
VL - 18
ER -
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@article{2008_Trofimov,
author = {Boris Aleksandrovich Trofimov and Sergey Franzevich Vasilevskii and Nina Kuzminichna Gusarova and Svetlana Filippovna Malysheva and Denis Sergeevich Baranov and Victor Il'ich Mamatyuk and Yuriy Vasil'evich Gatilov},
title = {Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.010},
number = {6},
pages = {318--319},
doi = {10.1016/j.mencom.2008.11.010}
}
MLA
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Trofimov, Boris Aleksandrovich, et al. “Complex of tris(Z-styryl)phosphine with PdCl2 as a new catalyst for the Sonogashira reaction.” Mendeleev Communications, vol. 18, no. 6, Nov. 2008, pp. 318-319. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.010.

Abstract

The complex [(Z-PhCH=CH)3P]2PdCl2 synthesized from tris(Z-styryl)phosphine and PdCl2 (DMF, 90 °C, 15min, yield 50%) is an active catalyst in the Sonogashira reaction (coupling between 1-ethynyl-4-nitrobenzene and 1-iodoanthra-9,10-quinone) and its activity is comparable with that of the complex [Ph3P]2PdCl2, the most common catalyst for this type of reactions.

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