Home / Publications / o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones

o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones

Margarita Aleksandrovna Lapitskaya 1
Margarita Aleksandrovna Lapitskaya
, 
Ljudmila Leonidovna Vasiljeva 1
Ljudmila Leonidovna Vasiljeva
, 
Kazimir Konstantinovich Pivnitsky 1
Kazimir Konstantinovich Pivnitsky
10.1016/j.mencom.2008.11.007
Published 2008-11-01
Communication , Volume 18, Issue 6, 309-311
16
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Lapitskaya M. A., Vasiljeva L. L., Pivnitsky K. K. o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 309-311.
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Lapitskaya M. A., Vasiljeva L. L., Pivnitsky K. K. o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 309-311.
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TY - JOUR
DO - 10.1016/j.mencom.2008.11.007
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.007
TI - o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones
T2 - Mendeleev Communications
AU - Lapitskaya, Margarita Aleksandrovna
AU - Vasiljeva, Ljudmila Leonidovna
AU - Pivnitsky, Kazimir Konstantinovich
PY - 2008
DA - 2008/11/01
PB - Mendeleev Communications
SP - 309-311
IS - 6
VL - 18
ER -
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@article{2008_Lapitskaya,
author = {Margarita Aleksandrovna Lapitskaya and Ljudmila Leonidovna Vasiljeva and Kazimir Konstantinovich Pivnitsky},
title = {o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.007},
number = {6},
pages = {309--311},
doi = {10.1016/j.mencom.2008.11.007}
}
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Lapitskaya, Margarita Aleksandrovna, et al. “o-Iodoxybenzoic acid in dimethylformamide as a convenient reagent for the oxidation of alcohols to aldehydes and ketones.” Mendeleev Communications, vol. 18, no. 6, Nov. 2008, pp. 309-311. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.007.

Abstract

DMF dissolves o-iodoxybenzoic acid (up to 0.1mol dm−3) and, therefore, is a solvent of choice for the reactions with o-iodoxybenzoic acid simplifying significantly a product isolation procedure due to a higher volatility. The reaction rate and selectivity of the oxidation of alcohols to corresponding carbonyl compounds with o-iodoxybenzoic acid in DMF are close to those in DMSO.

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