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5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes

Konstantin Nikolaevich Shavrin 1
Konstantin Nikolaevich Shavrin
, 
Valentin Dmitrievich Gvozdev 1
Valentin Dmitrievich Gvozdev
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1016/j.mencom.2008.11.003
Published 2008-11-01
Communication , Volume 18, Issue 6, 300-301
18
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Shavrin K. N., Gvozdev V. D., Nefedov O. M. 5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 300-301.
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Shavrin K. N., Gvozdev V. D., Nefedov O. M. 5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes // Mendeleev Communications. 2008. Vol. 18. No. 6. pp. 300-301.
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TY - JOUR
DO - 10.1016/j.mencom.2008.11.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.003
TI - 5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes
T2 - Mendeleev Communications
AU - Shavrin, Konstantin Nikolaevich
AU - Gvozdev, Valentin Dmitrievich
AU - Nefedov, Oleg Matveevich
PY - 2008
DA - 2008/11/01
PB - Mendeleev Communications
SP - 300-301
IS - 6
VL - 18
ER -
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@article{2008_Shavrin,
author = {Konstantin Nikolaevich Shavrin and Valentin Dmitrievich Gvozdev and Oleg Matveevich Nefedov},
title = {5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Nov},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.003},
number = {6},
pages = {300--301},
doi = {10.1016/j.mencom.2008.11.003}
}
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Shavrin, Konstantin Nikolaevich, et al. “5-Methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines in the reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2- and 1,3-diaminoalkanes.” Mendeleev Communications, vol. 18, no. 6, Nov. 2008, pp. 300-301. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.11.003.

Abstract

Unusual reactions of 1-(alk-1-ynyl)-1-chlorocyclopropanes with lithium derivatives of 1,2-diaminoethane, 1,3-diaminopropane and 1-methylamino-3-aminopropane in THF at 20 °C give previously unknown 5-methylenehexahydropyrrolo[1,2-a]imidazoles and 6-methyleneoctahydropyrrolo[1,2-a]pyrimidines with up to 60% yields.

References

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