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Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides

Nina Kuzminichna Gusarova ¹

Nina Kuzminichna Gusarova

Svetlana Filippovna Malysheva ¹

Svetlana Filippovna Malysheva

Vladimir Anatol'evich Kuimov ¹

Vladimir Anatol'evich Kuimov

Natalia Alekseevna Belogorlova ¹

Natalia Alekseevna Belogorlova

Valentina L'vovna Mikhailenko ¹

Valentina L'vovna Mikhailenko

Boris Aleksandrovich Trofimov ¹

Boris Aleksandrovich Trofimov

¹ A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

10.1016/j.mencom.2008.09.011

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Published 2008-09-15

Communication , Volume 18, Issue 5, 260-261

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Gusarova N. K. et al. Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides // Mendeleev Communications. 2008. Vol. 18. No. 5. pp. 260-261.

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Gusarova N. K., Malysheva S. F., Kuimov V. A., Belogorlova N. A., Mikhailenko V. L., Trofimov B. A. Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides // Mendeleev Communications. 2008. Vol. 18. No. 5. pp. 260-261.

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TY - JOUR

DO - 10.1016/j.mencom.2008.09.011

UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.011

TI - Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides

T2 - Mendeleev Communications

AU - Gusarova, Nina Kuzminichna

AU - Malysheva, Svetlana Filippovna

AU - Kuimov, Vladimir Anatol'evich

AU - Belogorlova, Natalia Alekseevna

AU - Mikhailenko, Valentina L'vovna

AU - Trofimov, Boris Aleksandrovich

PY - 2008

DA - 2008/09/15

PB - Mendeleev Communications

SP - 260-261

IS - 5

VL - 18

ER -

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@article{2008_Gusarova,

author = {Nina Kuzminichna Gusarova and Svetlana Filippovna Malysheva and Vladimir Anatol'evich Kuimov and Natalia Alekseevna Belogorlova and Valentina L'vovna Mikhailenko and Boris Aleksandrovich Trofimov},

title = {Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides},

journal = {Mendeleev Communications},

year = {2008},

volume = {18},

publisher = {Mendeleev Communications},

month = {Sep},

url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.011},

number = {5},

pages = {260--261},

doi = {10.1016/j.mencom.2008.09.011}

}

MLA

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Gusarova, Nina Kuzminichna, et al. “Nucleophilic additon of phosphine to 1-(tert-butyl)-4-vinylbenzene: a short-cut to bulky secondary and tertiary phosphines and their chalcogenides.” Mendeleev Communications, vol. 18, no. 5, Sep. 2008, pp. 260-261. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.011.

Abstract

Phosphine readily adds to 1-(tert-butyl)-4-vinylbenzene in the KOH–DMSO system (70–120°C, 3h, atmospheric pressure) to form bis[4-(tert-butyl)phenethyl]phosphine and tris[4-(tert-butyl)phenethyl]phosphine, which are further oxidized to corresponding phosphine oxides, sulfides and selenides.

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