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A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate

Dmitri Valer'evich Kazakov 1
Dmitri Valer'evich Kazakov
, 
Farit Èrikovich Safarov 1
Farit Èrikovich Safarov
, 
Valeri Petrovich Kazakov 1
Valeri Petrovich Kazakov
, 
Reinhardt Schmidt 2
Reinhardt Schmidt
10.1016/j.mencom.2008.09.006
Published 2008-09-15
Communication , Volume 18, Issue 5, 249-250
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Kazakov D. V. et al. A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate // Mendeleev Communications. 2008. Vol. 18. No. 5. pp. 249-250.
GOST all authors (up to 50) Copy
Kazakov D. V., Safarov F. È., Kazakov V. P., Schmidt R. A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate // Mendeleev Communications. 2008. Vol. 18. No. 5. pp. 249-250.
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TY - JOUR
DO - 10.1016/j.mencom.2008.09.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.006
TI - A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate
T2 - Mendeleev Communications
AU - Kazakov, Dmitri Valer'evich
AU - Safarov, Farit Èrikovich
AU - Kazakov, Valeri Petrovich
AU - Schmidt, Reinhardt
PY - 2008
DA - 2008/09/15
PB - Mendeleev Communications
SP - 249-250
IS - 5
VL - 18
ER -
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@article{2008_Kazakov,
author = {Dmitri Valer'evich Kazakov and Farit Èrikovich Safarov and Valeri Petrovich Kazakov and Reinhardt Schmidt},
title = {A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.006},
number = {5},
pages = {249--250},
doi = {10.1016/j.mencom.2008.09.006}
}
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Kazakov, Dmitri Valer'evich, et al. “A new bright chemiluminescent reaction: interaction of acetone with solid potassium peroxymonosulfate in the complex of europium nitrate.” Mendeleev Communications, vol. 18, no. 5, Sep. 2008, pp. 249-250. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.09.006.

Keywords

chemiluminescence
dioxiranes
lanthanides
singlet oxygen

Abstract

The interaction of acetone with a mixture of potassium peroxymonosulfate and europium nitrate hexahydrate powders at 90°C is accompanied by chemiluminescence due to the formation of excited Eu3+; dioxirane is proposed to be a key intermediate responsible for the chemiluminescence observed.

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