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Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen

Timur Rimovich Nugumanov 1
Timur Rimovich Nugumanov
Sergey Petrovich Ivanov 1
Sergey Petrovich Ivanov
Zoya Aleksandrovna Starikova 2
Zoya Aleksandrovna Starikova
Yuri Ilyich Murinov 1
Yuri Ilyich Murinov
Published 2008-07-17
CommunicationVolume 18, Issue 4, 223-224
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Nugumanov T. R. et al. Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 223-224.
GOST all authors (up to 50) Copy
Nugumanov T. R., Ivanov S. P., Starikova Z. A., Murinov Y. I. Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 223-224.
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TY - JOUR
DO - 10.1016/j.mencom.2008.07.020
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.020
TI - Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen
T2 - Mendeleev Communications
AU - Nugumanov, Timur Rimovich
AU - Ivanov, Sergey Petrovich
AU - Starikova, Zoya Aleksandrovna
AU - Murinov, Yuri Ilyich
PY - 2008
DA - 2008/07/17
PB - Mendeleev Communications
SP - 223-224
IS - 4
VL - 18
ER -
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@article{2008_Nugumanov,
author = {Timur Rimovich Nugumanov and Sergey Petrovich Ivanov and Zoya Aleksandrovna Starikova and Yuri Ilyich Murinov},
title = {Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.020},
number = {4},
pages = {223--224},
doi = {10.1016/j.mencom.2008.07.020}
}
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Nugumanov, Timur Rimovich, et al. “Oxidation of 5-hydroxy-6-methyluracil to 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione with molecular oxygen.” Mendeleev Communications, vol. 18, no. 4, Jul. 2008, pp. 223-224. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.020.

Abstract

The oxidation of 5-hydroxy-6-methyluracil with molecular oxygen in aqueous solutions in the presence of copper(II) chloride gave 5,5,6-trihydroxy-6-methylpyrimidine-2,4-dione in a quantitative yield.

References

1.
Metal complexes of uracils
Goodgame M., Jakubovic D.A.
Coordination Chemistry Reviews, 1987
3.
A haemocyanin model: a synthetic copper(I) complex having imidazole ligands and reversible dioxygen activity
Simmons M.G., Wilson L.J.
Journal of the Chemical Society Chemical Communications, 1978
4.
Reactions of dioxygen (O2) with mononuclear copper(I) complexes: temperature-dependent formation of peroxo- or oxo- (and dihydroxo-) bridged dicopper(II) complexes
Sanyal I., Mahroof-Tahir M., Nasir M.S., Ghosh P., Cohen B.I., Gultneh Y., Cruse R.W., Farooq A., Karlin K.D.
Inorganic Chemistry, 1992
5.
A new model for dioxygen binding in hemocyanin. Synthesis, characterization, and molecular structure of the .mu.-.eta.2:.eta.2 peroxo dinuclear copper(II) complexes, [Cu(HB(3,5-R2pz)3)]2(O2) (R = isopropyl and Ph)
Kitajima N., Fujisawa K., Fujimoto C., Morooka Y., Hashimoto S., Kitagawa T., Toriumi K., Tatsumi K., Nakamura A.
Journal of the American Chemical Society, 1992
7.
V. A. Myshkin and A. B. Bakirov, Oksimetiluratsil (ocherki eksperimental’noi farmakologii) [Hydroxymethyluracil (Essays on Experimental Pharmacology)], DAR, Ufa, 2001 (in Russian).
8.
Structure of a Duplex DNA Containing a Thymine Glycol Residue in Solution*
9.
Reactions of hydrogen peroxide and some of its derivatives with uracil, thymine, and thymidine 5'-phosphate
11.
Mechanism of the radiation-induced degradation of nucleic acids.
Scholes G., Ward J.F., Weiss J.
Journal of Molecular Biology, 1960
13.
Pulse radiolysis studies of uracil and its derivatives. Primary species attack
Greenstock C.L., Hunt J.W., Ng M.
Transactions of the Faraday Society, 1969
14.
10.1016/j.mencom.2008.07.020_bib11_4
Ducolomb
Bull. Soc. Chim. Fr., 1973
15.
Radiolysis of pyrimidines in aqueous solutions. Part 2.—Product formation in the interaction of e–aq, ·H, ·OH and Cl–2· with uracil
Infante G.A., Jirathana P., Fendler E.J., Fendler J.H.
Journal of the Chemical Society Faraday Transactions 1 Physical Chemistry in Condensed Phases, 1974
19.
10.1016/j.mencom.2008.07.020_bib12
Krivonogov
Khim. -Farm. Zh., 1993
20.
10.1016/j.mencom.2008.07.020_bib13
Ivanov
Bash. Khim. Zh., 2007