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Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products

Andrei Valentinovich Stepanov 1
Andrei Valentinovich Stepanov
, 
Electron Aleksandrovich Mistryukov 1
Electron Aleksandrovich Mistryukov
10.1016/j.mencom.2008.07.017
Published 2008-07-17
Communication , Volume 18, Issue 4, 215-216
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Stepanov A. V., Mistryukov E. A. Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 215-216.
GOST all authors (up to 50) Copy
Stepanov A. V., Mistryukov E. A. Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 215-216.
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TY - JOUR
DO - 10.1016/j.mencom.2008.07.017
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.017
TI - Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products
T2 - Mendeleev Communications
AU - Stepanov, Andrei Valentinovich
AU - Mistryukov, Electron Aleksandrovich
PY - 2008
DA - 2008/07/17
PB - Mendeleev Communications
SP - 215-216
IS - 4
VL - 18
ER -
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@article{2008_Stepanov,
author = {Andrei Valentinovich Stepanov and Electron Aleksandrovich Mistryukov},
title = {Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.017},
number = {4},
pages = {215--216},
doi = {10.1016/j.mencom.2008.07.017}
}
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Stepanov, Andrei Valentinovich, and Electron Aleksandrovich Mistryukov. “Aluminium–isopropanol reduction of tert-nitronitriles: an unusual structure of the reduction products.” Mendeleev Communications, vol. 18, no. 4, Jul. 2008, pp. 215-216. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.017.

Abstract

The reduction of γ-nitronitriles with aluminium–isopropanol results in a cyclic product, strongly O-nucleophilic iminonitronium, which is resistant to further reduction.

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