Home / Publications / Electrophilic components in the electrochemical acetoxylation of substituted arenes

Electrophilic components in the electrochemical acetoxylation of substituted arenes

Alexander Valeryevich Burasov 1
Alexander Valeryevich Burasov
, 
Vladimir Anushavanovich Petrosyan 1
Vladimir Anushavanovich Petrosyan
10.1016/j.mencom.2008.07.008
Published 2008-07-17
Communication , Volume 18, Issue 4, 196-197
4
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Burasov A. V., Petrosyan V. A. Electrophilic components in the electrochemical acetoxylation of substituted arenes // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 196-197.
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Burasov A. V., Petrosyan V. A. Electrophilic components in the electrochemical acetoxylation of substituted arenes // Mendeleev Communications. 2008. Vol. 18. No. 4. pp. 196-197.
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TY - JOUR
DO - 10.1016/j.mencom.2008.07.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.008
TI - Electrophilic components in the electrochemical acetoxylation of substituted arenes
T2 - Mendeleev Communications
AU - Burasov, Alexander Valeryevich
AU - Petrosyan, Vladimir Anushavanovich
PY - 2008
DA - 2008/07/17
PB - Mendeleev Communications
SP - 196-197
IS - 4
VL - 18
ER -
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@article{2008_Burasov,
author = {Alexander Valeryevich Burasov and Vladimir Anushavanovich Petrosyan},
title = {Electrophilic components in the electrochemical acetoxylation of substituted arenes},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.008},
number = {4},
pages = {196--197},
doi = {10.1016/j.mencom.2008.07.008}
}
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Burasov, Alexander Valeryevich, and Vladimir Anushavanovich Petrosyan. “Electrophilic components in the electrochemical acetoxylation of substituted arenes.” Mendeleev Communications, vol. 18, no. 4, Jul. 2008, pp. 196-197. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.07.008.

Abstract

The mechanism of anodic acetoxylation of substituted arenes under conditions of undivided galvanostatic electrolysis in MeCN containing acetate is suggested and an important role of electrophilic components (AcOH or ZnCl2) catalyzing transformation of intermediate ipso-acetoxylated polysubstituted arenonium cations to corresponding ortho-acetoxylated arenonium cations, which give acetoxylation products after deprotonation, is experimentally proved.

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