Home / Publications / Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane

Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane

Alexander Yurevich Verat 1
Alexander Yurevich Verat
, 
Valery Grigor'evich Shtyrlin 1
Valery Grigor'evich Shtyrlin
, 
Boulat Imamutdinovich Khairutdinov 1
Boulat Imamutdinovich Khairutdinov
, 
Felix Dmitrievich Sokolov 1
Felix Dmitrievich Sokolov
, 
Luiza Nurmukhametovna Yamalieva 1
Luiza Nurmukhametovna Yamalieva
, 
Dmitry Borisovich Krivolapov 2
Dmitry Borisovich Krivolapov
, 
Nail Galievich Zabirov 1
Nail Galievich Zabirov
, 
Igor Anatol'evich Litvinov 2
Igor Anatol'evich Litvinov
, 
10.1016/j.mencom.2008.05.013
Published 2008-05-14
Communication , Volume 18, Issue 3, 150-152
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Verat A. Y. et al. Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane // Mendeleev Communications. 2008. Vol. 18. No. 3. pp. 150-152.
GOST all authors (up to 50) Copy
Verat A. Y., Shtyrlin V. G., Khairutdinov B. I., Sokolov F. D., Yamalieva L. N., Krivolapov D. B., Zabirov N. G., Litvinov I. A., Klochkov V. V. Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane // Mendeleev Communications. 2008. Vol. 18. No. 3. pp. 150-152.
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TY - JOUR
DO - 10.1016/j.mencom.2008.05.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.013
TI - Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane
T2 - Mendeleev Communications
AU - Verat, Alexander Yurevich
AU - Shtyrlin, Valery Grigor'evich
AU - Khairutdinov, Boulat Imamutdinovich
AU - Sokolov, Felix Dmitrievich
AU - Yamalieva, Luiza Nurmukhametovna
AU - Krivolapov, Dmitry Borisovich
AU - Zabirov, Nail Galievich
AU - Litvinov, Igor Anatol'evich
AU - Klochkov, Vladimir Vasil'evich
PY - 2008
DA - 2008/05/14
PB - Mendeleev Communications
SP - 150-152
IS - 3
VL - 18
ER -
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@article{2008_Verat,
author = {Alexander Yurevich Verat and Valery Grigor'evich Shtyrlin and Boulat Imamutdinovich Khairutdinov and Felix Dmitrievich Sokolov and Luiza Nurmukhametovna Yamalieva and Dmitry Borisovich Krivolapov and Nail Galievich Zabirov and Igor Anatol'evich Litvinov and Vladimir Vasil'evich Klochkov},
title = {Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.013},
number = {3},
pages = {150--152},
doi = {10.1016/j.mencom.2008.05.013}
}
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Verat, Alexander Yurevich, et al. “Dynamic behaviour of the complex [Ni{PhC(S)NP(O)(OPri)2-O,S}2-{PhC(S)NHP(O)(OPri)2-O}2] in deuterotrichloromethane.” Mendeleev Communications, vol. 18, no. 3, May. 2008, pp. 150-152. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.013.

Abstract

The title complex has been studied by 1H and 31P NMR spectroscopy and found to undergo reversible dissociation of its neutral ligands and interconversion of its neutral and anionic ligands; the kinetic parameters of these processes and the crystal structure of the complex were determined; a new ligand exchange mechanism with unusual high spin–low spin transition during the ligand dissociation was suggested.

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