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Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide)

Dmitry Anatol'evich Tatarinov 1, 2
Dmitry Anatol'evich Tatarinov
, 
Vladimir Fedorovich Mironov 1, 2
Vladimir Fedorovich Mironov
, 
Elena Nikolaevna Varaksina 1
Elena Nikolaevna Varaksina
, 
Dmitry Borisovich Krivolapov 1
Dmitry Borisovich Krivolapov
, 
Igor Anatol'evich Litvinov 1
Igor Anatol'evich Litvinov
, 
Rashid Zagitovich Musin 1
Rashid Zagitovich Musin
, 
Boris Ivanovich Buzykin 1
Boris Ivanovich Buzykin
, 
Aleksandr Ivanovich Konovalov 1, 2
Aleksandr Ivanovich Konovalov
10.1016/j.mencom.2008.05.012
Published 2008-05-14
Communication , Volume 18, Issue 3, 147-149
8
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Tatarinov D. A. et al. Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide) // Mendeleev Communications. 2008. Vol. 18. No. 3. pp. 147-149.
GOST all authors (up to 50) Copy
Tatarinov D. A., Mironov V. F., Varaksina E. N., Krivolapov D. B., Litvinov I. A., Musin R. Z., Buzykin B. I., Konovalov A. I. Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide) // Mendeleev Communications. 2008. Vol. 18. No. 3. pp. 147-149.
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TY - JOUR
DO - 10.1016/j.mencom.2008.05.012
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.012
TI - Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide)
T2 - Mendeleev Communications
AU - Tatarinov, Dmitry Anatol'evich
AU - Mironov, Vladimir Fedorovich
AU - Varaksina, Elena Nikolaevna
AU - Krivolapov, Dmitry Borisovich
AU - Litvinov, Igor Anatol'evich
AU - Musin, Rashid Zagitovich
AU - Buzykin, Boris Ivanovich
AU - Konovalov, Aleksandr Ivanovich
PY - 2008
DA - 2008/05/14
PB - Mendeleev Communications
SP - 147-149
IS - 3
VL - 18
ER -
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@article{2008_Tatarinov,
author = {Dmitry Anatol'evich Tatarinov and Vladimir Fedorovich Mironov and Elena Nikolaevna Varaksina and Dmitry Borisovich Krivolapov and Igor Anatol'evich Litvinov and Rashid Zagitovich Musin and Boris Ivanovich Buzykin and Aleksandr Ivanovich Konovalov},
title = {Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide)},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {May},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.012},
number = {3},
pages = {147--149},
doi = {10.1016/j.mencom.2008.05.012}
}
MLA
Cite this
MLA Copy
Tatarinov, Dmitry Anatol'evich, et al. “Unusual reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with tetramethylenebis(magnesium bromide).” Mendeleev Communications, vol. 18, no. 3, May. 2008, pp. 147-149. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.05.012.

Abstract

The reaction of 8-chloro-2-cyclohexyl-4-phenylbenzo[e]-1,2-oxaphosphinine-2-oxide with ethyl- and phenylmagnesium bromides and tetramethylenebis(magnesium bromide) is a versatile approach to the synthesis of unsymmetrical phosphine oxides. With the latter Grignard reagent, an unusual phosphorus–carbon cleavage also occurs to yield a pentacoordinate phosphorus derivative, 2,3,8,9-bis(4-chlorobenzo)-6-cyclohexyl-6,9-diphenyl-1,7-dioxa-6-phosphaspiro[5.5]deca-1,9-diene.

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