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Absolute configuration of a chiral proton sponge

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Alexander Fedorovich Pozharskii 2
Alexander Fedorovich Pozharskii
,  , 
Konstantin Alexandrovich Lyssenko 3
Konstantin Alexandrovich Lyssenko
, 
Gulnara Konstantinovna Kadorkina 1
Gulnara Konstantinovna Kadorkina
, 
Alexander Vasil'evich Degtyarev 2
Alexander Vasil'evich Degtyarev
, 
Orudzh Garib ogly Nabiev 1
Orudzh Garib ogly Nabiev
, 
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
10.1016/j.mencom.2008.03.011
Published 2008-03-18
Communication , Volume 18, Issue 2, 86-87
3
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Kostyanovsky R. G. et al. Absolute configuration of a chiral proton sponge // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 86-87.
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Kostyanovsky R. G., Pozharskii A. F., Nelyubina Y. V., Lyssenko K. A., Kadorkina G. K., Degtyarev A. V., Nabiev O. G. O., Chervin I. I. Absolute configuration of a chiral proton sponge // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 86-87.
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TY - JOUR
DO - 10.1016/j.mencom.2008.03.011
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.011
TI - Absolute configuration of a chiral proton sponge
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Pozharskii, Alexander Fedorovich
AU - Nelyubina, Yulia Vladimirovna
AU - Lyssenko, Konstantin Alexandrovich
AU - Kadorkina, Gulnara Konstantinovna
AU - Degtyarev, Alexander Vasil'evich
AU - Nabiev, Orudzh Garib ogly
AU - Chervin, Ivan Ivanovich
PY - 2008
DA - 2008/03/18
PB - Mendeleev Communications
SP - 86-87
IS - 2
VL - 18
ER -
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@article{2008_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Alexander Fedorovich Pozharskii and Yulia Vladimirovna Nelyubina and Konstantin Alexandrovich Lyssenko and Gulnara Konstantinovna Kadorkina and Alexander Vasil'evich Degtyarev and Orudzh Garib ogly Nabiev and Ivan Ivanovich Chervin},
title = {Absolute configuration of a chiral proton sponge},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.011},
number = {2},
pages = {86--87},
doi = {10.1016/j.mencom.2008.03.011}
}
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Kostyanovsky, Remir Grigorevich, et al. “Absolute configuration of a chiral proton sponge.” Mendeleev Communications, vol. 18, no. 2, Mar. 2008, pp. 86-87. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.011.

Abstract

By the spontaneous resolution of racemic compound 1,8-bis(dimethylamino)-2-(α-hydroxy-α-phenylethyl)naphthalene (±)-1, enantiomer (–)-1 was obtained; its treatment with C5H5N·HBr resulted in the formation of proton sponge (–)-2; the absolute configurations of (R)-(–)-2 and, as a consequence, (R)-(–)-1 were determined by XRD analysis.

References

1.
Kostyanovsky R.G., Pozharskii A.F., Kadorkina G.K., Nabiev O.G., Degtyarev A.V., Malyshev O.R.
Mendeleev Communications, 2007
4.
Proton sponge phosphines: electrospray-active ligands
Farrer N.J., McDonald R., McIndoe J.S.
Dalton Transactions, 2006
5.
10.1016/j.mencom.2008.03.011_bib5
Ozeryanskii
Izv. Akad. Nauk, Ser. Khim., 2006