Home / Publications / Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane

Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane

Roman Nikolaevich Naumov 1
Roman Nikolaevich Naumov
, 
Andrey Anatol'evich Karasik 1
Andrey Anatol'evich Karasik
, 
Kirill Borisovich Kanunnikov 1
Kirill Borisovich Kanunnikov
, 
Artem Vladimirovich Kozlov 1
Artem Vladimirovich Kozlov
, 
Shamil Kamil'evich Latypov 1
Shamil Kamil'evich Latypov
, 
Konstantin Valentinovich Domasevitch 2
Konstantin Valentinovich Domasevitch
, 
Evamarie Hey-Hawkins 3
Evamarie Hey-Hawkins
, 
10.1016/j.mencom.2008.03.008
Published 2008-03-18
Communication , Volume 18, Issue 2, 80-81
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Naumov R. N. et al. Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 80-81.
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Naumov R. N., Karasik A. A., Kanunnikov K. B., Kozlov A. V., Latypov S. K., Domasevitch K. V., Hey-Hawkins E., Sinyashin O. G. Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 80-81.
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TY - JOUR
DO - 10.1016/j.mencom.2008.03.008
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.008
TI - Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane
T2 - Mendeleev Communications
AU - Naumov, Roman Nikolaevich
AU - Karasik, Andrey Anatol'evich
AU - Kanunnikov, Kirill Borisovich
AU - Kozlov, Artem Vladimirovich
AU - Latypov, Shamil Kamil'evich
AU - Domasevitch, Konstantin Valentinovich
AU - Hey-Hawkins, Evamarie
AU - Sinyashin, Oleg Gerol'dovich
PY - 2008
DA - 2008/03/18
PB - Mendeleev Communications
SP - 80-81
IS - 2
VL - 18
ER -
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@article{2008_Naumov,
author = {Roman Nikolaevich Naumov and Andrey Anatol'evich Karasik and Kirill Borisovich Kanunnikov and Artem Vladimirovich Kozlov and Shamil Kamil'evich Latypov and Konstantin Valentinovich Domasevitch and Evamarie Hey-Hawkins and Oleg Gerol'dovich Sinyashin},
title = {Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.008},
number = {2},
pages = {80--81},
doi = {10.1016/j.mencom.2008.03.008}
}
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Naumov, Roman Nikolaevich, et al. “Synthesis of a chiral macrocyclic tetraphosphine –1,9-di-R,R(and S,S)-α-methylbenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-(RSSR)-tetraphosphacyclohexadecane.” Mendeleev Communications, vol. 18, no. 2, Mar. 2008, pp. 80-81. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.008.

Keywords

Chiral macrocyclic phosphine
self-assembly
stereoselectivity

Abstract

Two enantiomers of the title compound containing six chiral atoms have been synthesised via stereoselective covalent self-assembly of two diphosphinopropane, four formaldehyde and two primary amine molecules.

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