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Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms

Boris Grigor'evich Zavin 1
Boris Grigor'evich Zavin
, 
Natalya Vasil'evna Sergienko 1
Natalya Vasil'evna Sergienko
, 
Alexander Aleksandrovich Korlyukov 1
Alexander Aleksandrovich Korlyukov
, 
Victor Davidovich Myakushev 2
Victor Davidovich Myakushev
, 
Mikhail Yuvenal'evich Antipin 1
Mikhail Yuvenal'evich Antipin
10.1016/j.mencom.2008.03.006
Published 2008-03-18
Communication , Volume 18, Issue 2, 76-77
7
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Zavin B. G. et al. Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 76-77.
GOST all authors (up to 50) Copy
Zavin B. G., Sergienko N. V., Korlyukov A. A., Myakushev V. D., Antipin M. Y. Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 76-77.
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TY - JOUR
DO - 10.1016/j.mencom.2008.03.006
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.006
TI - Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms
T2 - Mendeleev Communications
AU - Zavin, Boris Grigor'evich
AU - Sergienko, Natalya Vasil'evna
AU - Korlyukov, Alexander Aleksandrovich
AU - Myakushev, Victor Davidovich
AU - Antipin, Mikhail Yuvenal'evich
PY - 2008
DA - 2008/03/18
PB - Mendeleev Communications
SP - 76-77
IS - 2
VL - 18
ER -
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@article{2008_Zavin,
author = {Boris Grigor'evich Zavin and Natalya Vasil'evna Sergienko and Alexander Aleksandrovich Korlyukov and Victor Davidovich Myakushev and Mikhail Yuvenal'evich Antipin},
title = {Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.006},
number = {2},
pages = {76--77},
doi = {10.1016/j.mencom.2008.03.006}
}
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Zavin, Boris Grigor'evich, et al. “Ion exchange in bimetallic cage organosiloxanes incorporating copper and alkali metal atoms.” Mendeleev Communications, vol. 18, no. 2, Mar. 2008, pp. 76-77. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.006.

Abstract

The globular metallic cage organosiloxanes [RSiO2]12[Cu4M4] (where R=Me, CH2=CH or Ph and M=Na or K) can be converted to the corresponding alkaline Li derivatives in an ion-exchange reaction with LiCl under mild conditions (in up to 79% yields). The [RSiO2]12Cu4Li4 compounds have been synthesised and their structures have been studied by X-ray diffraction analysis.

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