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Delocalized methoxyacetone radical cation: structure and reactivity

Kirill Borisovich Nuzhdin 1
Kirill Borisovich Nuzhdin
, 
Vladimir Isaevich Feldman 1, 2
Vladimir Isaevich Feldman
, 
Aleksey Viktorovich Kobzarenko 1
Aleksey Viktorovich Kobzarenko
10.1016/j.mencom.2008.03.003
Published 2008-03-18
Communication , Volume 18, Issue 2, 69-70
9
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Nuzhdin K. B., Feldman V. I., Kobzarenko A. V. Delocalized methoxyacetone radical cation: structure and reactivity // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 69-70.
GOST all authors (up to 50) Copy
Nuzhdin K. B., Feldman V. I., Kobzarenko A. V. Delocalized methoxyacetone radical cation: structure and reactivity // Mendeleev Communications. 2008. Vol. 18. No. 2. pp. 69-70.
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TY - JOUR
DO - 10.1016/j.mencom.2008.03.003
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.003
TI - Delocalized methoxyacetone radical cation: structure and reactivity
T2 - Mendeleev Communications
AU - Nuzhdin, Kirill Borisovich
AU - Feldman, Vladimir Isaevich
AU - Kobzarenko, Aleksey Viktorovich
PY - 2008
DA - 2008/03/18
PB - Mendeleev Communications
SP - 69-70
IS - 2
VL - 18
ER -
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@article{2008_Nuzhdin,
author = {Kirill Borisovich Nuzhdin and Vladimir Isaevich Feldman and Aleksey Viktorovich Kobzarenko},
title = {Delocalized methoxyacetone radical cation: structure and reactivity},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Mar},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.003},
number = {2},
pages = {69--70},
doi = {10.1016/j.mencom.2008.03.003}
}
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Nuzhdin, Kirill Borisovich, et al. “Delocalized methoxyacetone radical cation: structure and reactivity.” Mendeleev Communications, vol. 18, no. 2, Mar. 2008, pp. 69-70. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.03.003.

Keywords

EPR
methoxyacetone
radical cation

Abstract

The radical cation (RC) of methoxyacetone exhibits a delocalization of spin density between two oxygen atoms with considerable spin population on methylene hydrogen atoms, which results in the selective deprotonation of this RC.

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