Home / Publications / Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

Vladimir Dmitrievich Kiselev 1
Vladimir Dmitrievich Kiselev
10.1016/j.mencom.2008.01.022
Published 2008-01-14
Communication , Volume 18, Issue 1, 59-61
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Kiselev V. D. Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 59-61.
GOST all authors (up to 50) Copy
Kiselev V. D. Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 59-61.
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TY - JOUR
DO - 10.1016/j.mencom.2008.01.022
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.022
TI - Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion
T2 - Mendeleev Communications
AU - Kiselev, Vladimir Dmitrievich
PY - 2008
DA - 2008/01/14
PB - Mendeleev Communications
SP - 59-61
IS - 1
VL - 18
ER -
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@article{2008_Kiselev,
author = {Vladimir Dmitrievich Kiselev},
title = {Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.022},
number = {1},
pages = {59--61},
doi = {10.1016/j.mencom.2008.01.022}
}
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Kiselev, Vladimir Dmitrievich. “Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion.” Mendeleev Communications, vol. 18, no. 1, Jan. 2008, pp. 59-61. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.022.

Keywords

sulfenyl chloride; volume of activation; solvent effect; electrostriction; mechanism

Abstract

The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter ∂(1/ϵ)/∂p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene and cyclohexene have the slope about 20 times less.

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