Home / Publications / Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide

Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide

Marina Yu Dvorko 1
Marina Yu Dvorko
, 
Tat'yana Evgen'evna Glotova 1
Tat'yana Evgen'evna Glotova
, 
Alexander Ivanovich Albanov 1
Alexander Ivanovich Albanov
, 
Nina Nikolaevna Chipanina 1
Nina Nikolaevna Chipanina
, 
Olga Nikolaevna Kazheva 2
Olga Nikolaevna Kazheva
, 
Gennady Viktorovich Shilov 2
Gennady Viktorovich Shilov
, 
Oleg Anatol'evich Dyachenko 2
Oleg Anatol'evich Dyachenko
10.1016/j.mencom.2008.01.018
Published 2008-01-14
Communication , Volume 18, Issue 1, 48-50
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Dvorko M. Yu. et al. Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 48-50.
GOST all authors (up to 50) Copy
Dvorko M. Yu., Glotova T. E., Albanov A. I., Chipanina N. N., Kazheva O. N., Shilov G. V., Dyachenko O. A. Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 48-50.
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TY - JOUR
DO - 10.1016/j.mencom.2008.01.018
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.018
TI - Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide
T2 - Mendeleev Communications
AU - Dvorko, Marina Yu
AU - Glotova, Tat'yana Evgen'evna
AU - Albanov, Alexander Ivanovich
AU - Chipanina, Nina Nikolaevna
AU - Kazheva, Olga Nikolaevna
AU - Shilov, Gennady Viktorovich
AU - Dyachenko, Oleg Anatol'evich
PY - 2008
DA - 2008/01/14
PB - Mendeleev Communications
SP - 48-50
IS - 1
VL - 18
ER -
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@article{2008_Dvorko,
author = {Marina Yu Dvorko and Tat'yana Evgen'evna Glotova and Alexander Ivanovich Albanov and Nina Nikolaevna Chipanina and Olga Nikolaevna Kazheva and Gennady Viktorovich Shilov and Oleg Anatol'evich Dyachenko},
title = {Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.018},
number = {1},
pages = {48--50},
doi = {10.1016/j.mencom.2008.01.018}
}
MLA
Cite this
MLA Copy
Dvorko, Marina Yu., et al. “Chemo- and stereodirectivity of the reaction of thiocarbohydrazide with 1-acetyl-2-phenylacetylene: synthesis and structure of bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide.” Mendeleev Communications, vol. 18, no. 1, Jan. 2008, pp. 48-50. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.018.

Abstract

1-Acetyl-2-phenylacetylene reacts with thiocarbohydrazide under mild conditions to afford exclusively N2-(Z-s-trans), N3-(Z-s-cis)- bis(1-methyl-3-phenyl-2-propynylidene)carbonothioic dihydrazide in high yield (up to 92%); the structure of the compound has been confirmed by IR and NMR spectroscopy and X-ray analysis.

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