Home / Publications / New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode

New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode

Konstantin Alexandrovich Rufanov 1
Konstantin Alexandrovich Rufanov
, 
Anke Spannenberg 2
Anke Spannenberg
10.1016/j.mencom.2008.01.013
Published 2008-01-14
Communication , Volume 18, Issue 1, 32-34
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Rufanov K. A., Spannenberg A. New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 32-34.
GOST all authors (up to 50) Copy
Rufanov K. A., Spannenberg A. New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode // Mendeleev Communications. 2008. Vol. 18. No. 1. pp. 32-34.
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TY - JOUR
DO - 10.1016/j.mencom.2008.01.013
UR - https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.013
TI - New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode
T2 - Mendeleev Communications
AU - Rufanov, Konstantin Alexandrovich
AU - Spannenberg, Anke
PY - 2008
DA - 2008/01/14
PB - Mendeleev Communications
SP - 32-34
IS - 1
VL - 18
ER -
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@article{2008_Rufanov,
author = {Konstantin Alexandrovich Rufanov and Anke Spannenberg},
title = {New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode},
journal = {Mendeleev Communications},
year = {2008},
volume = {18},
publisher = {Mendeleev Communications},
month = {Jan},
url = {https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.013},
number = {1},
pages = {32--34},
doi = {10.1016/j.mencom.2008.01.013}
}
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Rufanov, Konstantin Alexandrovich, and Anke Spannenberg. “New rare-earth complexes with phosphonium bis(ylide) ligand [Ph2P(CH2)2]− and the first structural evidence for its bridging coordination mode.” Mendeleev Communications, vol. 18, no. 1, Jan. 2008, pp. 32-34. https://mendcomm.colab.ws/publications/10.1016/j.mencom.2008.01.013.

Abstract

A series of phosphonium bis(ylide) rare-earth complexes of the type Cp*M(byl)2 (M=Sc, Y, Dy, Yb and Lu; byl=[Ph2P(CH2)2]−) has been synthesised and in three cases (Dy, Yb and Lu) structurally characterised revealing realization alongside with the chelating coordination mode for byl, also, for the first time, the bridging mode in dimeric Dy-complex.

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